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Phosphinoindenyl and phosphazidoindenyl complexes of lanthanum and samarium: synthesis, characterisation, and hydroamination catalysis
The phosphinoindenyl rare-earth metal complexes [1-(Ph(2)P)-η(5)-C(9)H(6)](2)Ln(III)N(SiMe(3))(2), Ln = La (1-La), Sm (1-Sm), were prepared by heating two equivalents of 1-(Ph(2)P)C(9)H(7) with Ln(III)[N(SiMe(3))(2)](3) in toluene at 100 °C. The treatment of 1-La with one equivalent of benzonitrile...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8805144/ https://www.ncbi.nlm.nih.gov/pubmed/34988574 http://dx.doi.org/10.1039/d1dt03219d |