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A cuboidal [Cu(4)(SO(4))(4)] structure supported by β-picoline ligands
The solid-state structure of the cobalt–β-picoline–sulfate complex tetra-μ(3)-sulfato-tetrakis[bis(3-methylpyridine)cobalt(II)], [Co(4)(SO(4))(4)(C(6)H(7)N)(8)], is reported. The tetrameric cobalt cluster contains a cuboidal core comprised of four cobalt(II) cations and four sulfate anions at...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8819428/ https://www.ncbi.nlm.nih.gov/pubmed/35145733 http://dx.doi.org/10.1107/S2056989022000780 |
| Sumario: | The solid-state structure of the cobalt–β-picoline–sulfate complex tetra-μ(3)-sulfato-tetrakis[bis(3-methylpyridine)cobalt(II)], [Co(4)(SO(4))(4)(C(6)H(7)N)(8)], is reported. The tetrameric cobalt cluster contains a cuboidal core comprised of four cobalt(II) cations and four sulfate anions at alternate cube vertices. The cobalt corners are each capped with two β-picoline ligands. The sulfate anions adopt a rare [3.2110] bridging motif, and the cuboidal cluster is unprecedented in coordination chemistry. |
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