A cuboidal [Cu(4)(SO(4))(4)] structure supported by β-picoline ligands

The solid-state structure of the cobalt–β-picoline–sulfate complex tetra-μ(3)-sulfato-tetra­kis­[bis­(3-methyl­pyridine)­cobalt(II)], [Co(4)(SO(4))(4)(C(6)H(7)N)(8)], is reported. The tetra­meric cobalt cluster contains a cuboidal core comprised of four cobalt(II) cations and four sulfate anions at...

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Detalles Bibliográficos
Autores principales: Park, Ava M., Golen, James A., Manke, David R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Jerry P. Jasinski tribute
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8819428/
https://www.ncbi.nlm.nih.gov/pubmed/35145733
http://dx.doi.org/10.1107/S2056989022000780
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author Park, Ava M.
Golen, James A.
Manke, David R.
author_facet Park, Ava M.
Golen, James A.
Manke, David R.
author_sort Park, Ava M.
collection PubMed
description The solid-state structure of the cobalt–β-picoline–sulfate complex tetra-μ(3)-sulfato-tetra­kis­[bis­(3-methyl­pyridine)­cobalt(II)], [Co(4)(SO(4))(4)(C(6)H(7)N)(8)], is reported. The tetra­meric cobalt cluster contains a cuboidal core comprised of four cobalt(II) cations and four sulfate anions at alternate cube vertices. The cobalt corners are each capped with two β-picoline ligands. The sulfate anions adopt a rare [3.2110] bridging motif, and the cuboidal cluster is unprecedented in coordination chemistry.
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spelling pubmed-88194282022-02-09 A cuboidal [Cu(4)(SO(4))(4)] structure supported by β-picoline ligands Park, Ava M. Golen, James A. Manke, David R. Acta Crystallogr E Crystallogr Commun Jerry P. Jasinski tribute The solid-state structure of the cobalt–β-picoline–sulfate complex tetra-μ(3)-sulfato-tetra­kis­[bis­(3-methyl­pyridine)­cobalt(II)], [Co(4)(SO(4))(4)(C(6)H(7)N)(8)], is reported. The tetra­meric cobalt cluster contains a cuboidal core comprised of four cobalt(II) cations and four sulfate anions at alternate cube vertices. The cobalt corners are each capped with two β-picoline ligands. The sulfate anions adopt a rare [3.2110] bridging motif, and the cuboidal cluster is unprecedented in coordination chemistry. International Union of Crystallography 2022-01-28 /pmc/articles/PMC8819428/ /pubmed/35145733 http://dx.doi.org/10.1107/S2056989022000780 Text en © Park et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Jerry P. Jasinski tribute
Park, Ava M.
Golen, James A.
Manke, David R.
A cuboidal [Cu(4)(SO(4))(4)] structure supported by β-picoline ligands
title A cuboidal [Cu(4)(SO(4))(4)] structure supported by β-picoline ligands
title_full A cuboidal [Cu(4)(SO(4))(4)] structure supported by β-picoline ligands
title_fullStr A cuboidal [Cu(4)(SO(4))(4)] structure supported by β-picoline ligands
title_full_unstemmed A cuboidal [Cu(4)(SO(4))(4)] structure supported by β-picoline ligands
title_short A cuboidal [Cu(4)(SO(4))(4)] structure supported by β-picoline ligands
title_sort cuboidal [cu(4)(so(4))(4)] structure supported by β-picoline ligands
topic Jerry P. Jasinski tribute
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8819428/
https://www.ncbi.nlm.nih.gov/pubmed/35145733
http://dx.doi.org/10.1107/S2056989022000780
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