Bis[3-(anthracen-9-yl)pentane-2,4-dionato-κ(2) O,O′](N,N-di­methyl­formamide-κO)[tris­(pyrazol-1-yl-κN (2))hydroborato]europium(III)

The title compound, [Eu(C(9)H(10)BN(6))(C(19)H(15)O(2))(2)(C(3)H(7)NO)] or [TpEu(Anthracac)(2)(DMF)], was synthesized by reaction of a tris­(pyrazol­yl)borate (Tp(−)) Eu(3+) complex with 3-(anthracen-9-yl)pentane-2,4-dione (HAnthracac) in the presence of tri­ethyl­amine. In the title compound, Eu(3+...

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Autores principales: Mikhalyova, Elena A., Zeller, Matthias, Jasinski, Jerry P., Kaur, Manpreet, Addison, Anthony W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2022
Materias:
Jerry P. Jasinski tribute
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8819440/
https://www.ncbi.nlm.nih.gov/pubmed/35145732
http://dx.doi.org/10.1107/S2056989022000676
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author Mikhalyova, Elena A.
Zeller, Matthias
Jasinski, Jerry P.
Kaur, Manpreet
Addison, Anthony W.
author_facet Mikhalyova, Elena A.
Zeller, Matthias
Jasinski, Jerry P.
Kaur, Manpreet
Addison, Anthony W.
author_sort Mikhalyova, Elena A.
collection PubMed
description The title compound, [Eu(C(9)H(10)BN(6))(C(19)H(15)O(2))(2)(C(3)H(7)NO)] or [TpEu(Anthracac)(2)(DMF)], was synthesized by reaction of a tris­(pyrazol­yl)borate (Tp(−)) Eu(3+) complex with 3-(anthracen-9-yl)pentane-2,4-dione (HAnthracac) in the presence of tri­ethyl­amine. In the title compound, Eu(3+) is located in an octa­vertex square-pyramidal coordination environment. In the two Anthracac(−) ligands, the anthracene and nearly planar acetyl­acetonate fragments are almost orthogonal. Neighboring mol­ecules of TpEu(Anthracac)(2)(DMF) are connected in the crystal by inter­molecular van der Waals inter­actions, while π-stacking inter­actions are limited to the edges of two anthracene rings.
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spelling pubmed-88194402022-02-09 Bis[3-(anthracen-9-yl)pentane-2,4-dionato-κ(2) O,O′](N,N-di­methyl­formamide-κO)[tris­(pyrazol-1-yl-κN (2))hydroborato]europium(III) Mikhalyova, Elena A. Zeller, Matthias Jasinski, Jerry P. Kaur, Manpreet Addison, Anthony W. Acta Crystallogr E Crystallogr Commun Jerry P. Jasinski tribute The title compound, [Eu(C(9)H(10)BN(6))(C(19)H(15)O(2))(2)(C(3)H(7)NO)] or [TpEu(Anthracac)(2)(DMF)], was synthesized by reaction of a tris­(pyrazol­yl)borate (Tp(−)) Eu(3+) complex with 3-(anthracen-9-yl)pentane-2,4-dione (HAnthracac) in the presence of tri­ethyl­amine. In the title compound, Eu(3+) is located in an octa­vertex square-pyramidal coordination environment. In the two Anthracac(−) ligands, the anthracene and nearly planar acetyl­acetonate fragments are almost orthogonal. Neighboring mol­ecules of TpEu(Anthracac)(2)(DMF) are connected in the crystal by inter­molecular van der Waals inter­actions, while π-stacking inter­actions are limited to the edges of two anthracene rings. International Union of Crystallography 2022-01-28 /pmc/articles/PMC8819440/ /pubmed/35145732 http://dx.doi.org/10.1107/S2056989022000676 Text en © Mikhalyova et al. 2022 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Jerry P. Jasinski tribute
Mikhalyova, Elena A.
Zeller, Matthias
Jasinski, Jerry P.
Kaur, Manpreet
Addison, Anthony W.
Bis[3-(anthracen-9-yl)pentane-2,4-dionato-κ(2) O,O′](N,N-di­methyl­formamide-κO)[tris­(pyrazol-1-yl-κN (2))hydroborato]europium(III)
title Bis[3-(anthracen-9-yl)pentane-2,4-dionato-κ(2) O,O′](N,N-di­methyl­formamide-κO)[tris­(pyrazol-1-yl-κN (2))hydroborato]europium(III)
title_full Bis[3-(anthracen-9-yl)pentane-2,4-dionato-κ(2) O,O′](N,N-di­methyl­formamide-κO)[tris­(pyrazol-1-yl-κN (2))hydroborato]europium(III)
title_fullStr Bis[3-(anthracen-9-yl)pentane-2,4-dionato-κ(2) O,O′](N,N-di­methyl­formamide-κO)[tris­(pyrazol-1-yl-κN (2))hydroborato]europium(III)
title_full_unstemmed Bis[3-(anthracen-9-yl)pentane-2,4-dionato-κ(2) O,O′](N,N-di­methyl­formamide-κO)[tris­(pyrazol-1-yl-κN (2))hydroborato]europium(III)
title_short Bis[3-(anthracen-9-yl)pentane-2,4-dionato-κ(2) O,O′](N,N-di­methyl­formamide-κO)[tris­(pyrazol-1-yl-κN (2))hydroborato]europium(III)
title_sort bis[3-(anthracen-9-yl)pentane-2,4-dionato-κ(2) o,o′](n,n-di­methyl­formamide-κo)[tris­(pyrazol-1-yl-κn (2))hydroborato]europium(iii)
topic Jerry P. Jasinski tribute
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8819440/
https://www.ncbi.nlm.nih.gov/pubmed/35145732
http://dx.doi.org/10.1107/S2056989022000676
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