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Scratch-Healing Behavior of Ice by Local Sublimation and Condensation

[Image: see text] We show that the surface of ice is scratch healing: micrometer-deep scratches in the ice surface spontaneously disappear by thermal relaxation on the time scale of roughly an hour. Following the dynamics and comparing it to different mass transfer mechanisms, we find that sublimati...

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Detalles Bibliográficos
Autores principales: Demmenie, Menno, Kolpakov, Paul, Nagata, Yuki, Woutersen, Sander, Bonn, Daniel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8819648/
https://www.ncbi.nlm.nih.gov/pubmed/35145575
http://dx.doi.org/10.1021/acs.jpcc.1c09590
Descripción
Sumario:[Image: see text] We show that the surface of ice is scratch healing: micrometer-deep scratches in the ice surface spontaneously disappear by thermal relaxation on the time scale of roughly an hour. Following the dynamics and comparing it to different mass transfer mechanisms, we find that sublimation from and condensation onto the ice surface is the dominant scratch-healing mechanism. The scratch-healing kinetics shows a strong temperature dependence, following an Arrhenius behavior with an activation energy of ΔE = 58.6 ± 4.6 kJ/mol, agreeing with the proposed sublimation mechanism and at odds with surface diffusion or fluid flow or evaporation–condensation from a quasi-liquid layer.