One-Pot Difunctionalization of Aryldiazonium Salts for Synthesis of para-Azophenols

A novel difunctionalization of aryldiazonium salts was realized for the one-step generation of symmetric and asymmetric p-azophenols. This approach is proceeded by the sequentially regioselective aromatic C-O and C-N bond construction under mild reaction conditions, unlocking a new reaction strategy...

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Detalles Bibliográficos
Autores principales: Liu, Zhenhua, Fang, Yang, Liu, Yi, Fu, Wei, Gan, Xingxing, Gao, Wen, Tang, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8826725/
https://www.ncbi.nlm.nih.gov/pubmed/35155368
http://dx.doi.org/10.3389/fchem.2022.818627
Descripción
Sumario:A novel difunctionalization of aryldiazonium salts was realized for the one-step generation of symmetric and asymmetric p-azophenols. This approach is proceeded by the sequentially regioselective aromatic C-O and C-N bond construction under mild reaction conditions, unlocking a new reaction strategy to facilitate the synthesis of p-azophenols.

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