One-Pot Difunctionalization of Aryldiazonium Salts for Synthesis of para-Azophenols

A novel difunctionalization of aryldiazonium salts was realized for the one-step generation of symmetric and asymmetric p-azophenols. This approach is proceeded by the sequentially regioselective aromatic C-O and C-N bond construction under mild reaction conditions, unlocking a new reaction strategy...

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Autores principales: Liu, Zhenhua, Fang, Yang, Liu, Yi, Fu, Wei, Gan, Xingxing, Gao, Wen, Tang, Bo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8826725/
https://www.ncbi.nlm.nih.gov/pubmed/35155368
http://dx.doi.org/10.3389/fchem.2022.818627
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author Liu, Zhenhua
Fang, Yang
Liu, Yi
Fu, Wei
Gan, Xingxing
Gao, Wen
Tang, Bo
author_facet Liu, Zhenhua
Fang, Yang
Liu, Yi
Fu, Wei
Gan, Xingxing
Gao, Wen
Tang, Bo
author_sort Liu, Zhenhua
collection PubMed
description A novel difunctionalization of aryldiazonium salts was realized for the one-step generation of symmetric and asymmetric p-azophenols. This approach is proceeded by the sequentially regioselective aromatic C-O and C-N bond construction under mild reaction conditions, unlocking a new reaction strategy to facilitate the synthesis of p-azophenols.
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spelling pubmed-88267252022-02-10 One-Pot Difunctionalization of Aryldiazonium Salts for Synthesis of para-Azophenols Liu, Zhenhua Fang, Yang Liu, Yi Fu, Wei Gan, Xingxing Gao, Wen Tang, Bo Front Chem Chemistry A novel difunctionalization of aryldiazonium salts was realized for the one-step generation of symmetric and asymmetric p-azophenols. This approach is proceeded by the sequentially regioselective aromatic C-O and C-N bond construction under mild reaction conditions, unlocking a new reaction strategy to facilitate the synthesis of p-azophenols. Frontiers Media S.A. 2022-01-26 /pmc/articles/PMC8826725/ /pubmed/35155368 http://dx.doi.org/10.3389/fchem.2022.818627 Text en Copyright © 2022 Liu, Fang, Liu, Fu, Gan, Gao and Tang. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Liu, Zhenhua
Fang, Yang
Liu, Yi
Fu, Wei
Gan, Xingxing
Gao, Wen
Tang, Bo
One-Pot Difunctionalization of Aryldiazonium Salts for Synthesis of para-Azophenols
title One-Pot Difunctionalization of Aryldiazonium Salts for Synthesis of para-Azophenols
title_full One-Pot Difunctionalization of Aryldiazonium Salts for Synthesis of para-Azophenols
title_fullStr One-Pot Difunctionalization of Aryldiazonium Salts for Synthesis of para-Azophenols
title_full_unstemmed One-Pot Difunctionalization of Aryldiazonium Salts for Synthesis of para-Azophenols
title_short One-Pot Difunctionalization of Aryldiazonium Salts for Synthesis of para-Azophenols
title_sort one-pot difunctionalization of aryldiazonium salts for synthesis of para-azophenols
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8826725/
https://www.ncbi.nlm.nih.gov/pubmed/35155368
http://dx.doi.org/10.3389/fchem.2022.818627
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