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Solvent coordination to palladium can invert the selectivity of oxidative addition
Reaction solvent was previously shown to influence the selectivity of Pd/P(t)Bu(3)-catalyzed Suzuki–Miyaura cross-couplings of chloroaryl triflates. The role of solvents has been hypothesized to relate to their polarity, whereby polar solvents stabilize anionic transition states involving [Pd(P(t)Bu...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2021
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8827013/ https://www.ncbi.nlm.nih.gov/pubmed/35282616 http://dx.doi.org/10.1039/d1sc05862b |