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Theoretical, chemical, and electrochemical studies of Equisetum arvense extract as an impactful inhibitor of steel corrosion in 2 M HCl electrolyte

A new type of Equisetum arvense aerial part (EAAP) extract was ready to be tested as a corrosion inhibitor for steel-based parts in Multi-stage flash (MSF) segments while the segments were being acid cleaned. The EAAP extract was identified using Fourier-transform infrared (FTIR) and High-performanc...

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Autores principales: Deyab, M. A., Mohsen, Q., Guo, Lei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8831498/
https://www.ncbi.nlm.nih.gov/pubmed/35145178
http://dx.doi.org/10.1038/s41598-022-06215-6
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author Deyab, M. A.
Mohsen, Q.
Guo, Lei
author_facet Deyab, M. A.
Mohsen, Q.
Guo, Lei
author_sort Deyab, M. A.
collection PubMed
description A new type of Equisetum arvense aerial part (EAAP) extract was ready to be tested as a corrosion inhibitor for steel-based parts in Multi-stage flash (MSF) segments while the segments were being acid cleaned. The EAAP extract was identified using Fourier-transform infrared (FTIR) and High-performance liquid chromatography (HPLC). When compared to the specimen exposed to blank solution, EAAP extract molecules covered about 97% of the carbon steel surface in 2 M HCl solution, and the corrosion rate was reduced to 0.58 ± 0.02 μg cm(−2) h(−1) at 300 mg l(−1). EAAP extract tends to have a blended impact on both anodic and cathodic sites on the surface of carbon steel. The thermodynamic activation factors are substantially higher in the presence of extract solution than in the absent of extract, demonstrating that the carbon steel surface would corrode slowly in the presence of EAAP extract. Theoretical models were used to validate the adsorption of EAAP extract on steel surfaces.
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spelling pubmed-88314982022-02-14 Theoretical, chemical, and electrochemical studies of Equisetum arvense extract as an impactful inhibitor of steel corrosion in 2 M HCl electrolyte Deyab, M. A. Mohsen, Q. Guo, Lei Sci Rep Article A new type of Equisetum arvense aerial part (EAAP) extract was ready to be tested as a corrosion inhibitor for steel-based parts in Multi-stage flash (MSF) segments while the segments were being acid cleaned. The EAAP extract was identified using Fourier-transform infrared (FTIR) and High-performance liquid chromatography (HPLC). When compared to the specimen exposed to blank solution, EAAP extract molecules covered about 97% of the carbon steel surface in 2 M HCl solution, and the corrosion rate was reduced to 0.58 ± 0.02 μg cm(−2) h(−1) at 300 mg l(−1). EAAP extract tends to have a blended impact on both anodic and cathodic sites on the surface of carbon steel. The thermodynamic activation factors are substantially higher in the presence of extract solution than in the absent of extract, demonstrating that the carbon steel surface would corrode slowly in the presence of EAAP extract. Theoretical models were used to validate the adsorption of EAAP extract on steel surfaces. Nature Publishing Group UK 2022-02-10 /pmc/articles/PMC8831498/ /pubmed/35145178 http://dx.doi.org/10.1038/s41598-022-06215-6 Text en © The Author(s) 2022 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Deyab, M. A.
Mohsen, Q.
Guo, Lei
Theoretical, chemical, and electrochemical studies of Equisetum arvense extract as an impactful inhibitor of steel corrosion in 2 M HCl electrolyte
title Theoretical, chemical, and electrochemical studies of Equisetum arvense extract as an impactful inhibitor of steel corrosion in 2 M HCl electrolyte
title_full Theoretical, chemical, and electrochemical studies of Equisetum arvense extract as an impactful inhibitor of steel corrosion in 2 M HCl electrolyte
title_fullStr Theoretical, chemical, and electrochemical studies of Equisetum arvense extract as an impactful inhibitor of steel corrosion in 2 M HCl electrolyte
title_full_unstemmed Theoretical, chemical, and electrochemical studies of Equisetum arvense extract as an impactful inhibitor of steel corrosion in 2 M HCl electrolyte
title_short Theoretical, chemical, and electrochemical studies of Equisetum arvense extract as an impactful inhibitor of steel corrosion in 2 M HCl electrolyte
title_sort theoretical, chemical, and electrochemical studies of equisetum arvense extract as an impactful inhibitor of steel corrosion in 2 m hcl electrolyte
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8831498/
https://www.ncbi.nlm.nih.gov/pubmed/35145178
http://dx.doi.org/10.1038/s41598-022-06215-6
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