Synergistic Approach toward Erbium-Passivated Triple-Anion Organic-Free Perovskite Solar Cells with Excellent Performance for Agrivoltaics Application

[Image: see text] All-inorganic perovskite solar cells (IPSCs) have gained massive attention due to their less instability against common degradation factors (light, heat, and moisture) than their organic–inorganic hybrid counterparts. Inorganic perovskites bear a general formula of CsPbX(3) (X = Cl, I, Br). The mixed halide CsPbIBr(2) perovskite possesses an intermediate band gap of 2.03 eV with enhanced stability, which is still available for photovoltaic applications and the research focus of this work. We present a synergistic approach of pre-heated solution dropping with inorganic additive inclusion to deposit the organic-free triple anion CsPbIBr(2) PSC. Erbium (Er)-passivated triple-anion CsI(PbBr(2))(0.97)(ErCl(3))(0.03) IPSCs with inorganic carrier selective layers (CTLs), that is, organic-free, are fabricated with enhanced carrier diffusion length and crystalline grain size while lessening the grain boundaries near perovskite active layer (PAL)-bulk/carrier selective interfaces. As a result, the trap-state densities within the perovskite bulk were suppressed with stabilized CTL/PAL interfaces for smooth and enhanced carrier transportation. Therefore, for the first time, we contradict the common belief of V(OC) loss due to halide segregation, as a nice V(OC) of about 1.34 V is achieved for an organic-free IPSC through enriching initial radiative efficiency, even when halide segregation is present. The optimized organic-free IPSC yielded a power conversion efficiency of 11.61% and a stabilized power output of 10.72%, which provides the potential opportunity to integrate into agrivoltaics (AgV) projects.