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Inorganometallics (Transition Metal–Metalloid Complexes) and Catalysis
[Image: see text] While the formation and breaking of transition metal (TM)–carbon bonds plays a pivotal role in the catalysis of organic compounds, the reactivity of inorganometallic species, that is, those involving the transition metal (TM)–metalloid (E) bond, is of key importance in most convers...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2021
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8832401/ https://www.ncbi.nlm.nih.gov/pubmed/34967210 http://dx.doi.org/10.1021/acs.chemrev.1c00417 |
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author | Marciniec, Bogdan Pietraszuk, Cezary Pawluć, Piotr Maciejewski, Hieronim |
author_facet | Marciniec, Bogdan Pietraszuk, Cezary Pawluć, Piotr Maciejewski, Hieronim |
author_sort | Marciniec, Bogdan |
collection | PubMed |
description | [Image: see text] While the formation and breaking of transition metal (TM)–carbon bonds plays a pivotal role in the catalysis of organic compounds, the reactivity of inorganometallic species, that is, those involving the transition metal (TM)–metalloid (E) bond, is of key importance in most conversions of metalloid derivatives catalyzed by TM complexes. This Review presents the background of inorganometallic catalysis and its development over the last 15 years. The results of mechanistic studies presented in the Review are related to the occurrence of TM–E and TM–H compounds as reactive intermediates in the catalytic transformations of selected metalloids (E = B, Si, Ge, Sn, As, Sb, or Te). The Review illustrates the significance of inorganometallics in catalysis of the following processes: addition of metalloid–hydrogen and metalloid–metalloid bonds to unsaturated compounds; activation and functionalization of C–H bonds and C–X bonds with hydrometalloids and bismetalloids; activation and functionalization of C–H bonds with vinylmetalloids, metalloid halides, and sulfonates; and dehydrocoupling of hydrometalloids. This first Review on inorganometallic catalysis sums up the developments in the catalytic methods for the synthesis of organometalloid compounds and their applications in advanced organic synthesis as a part of tandem reactions. |
format | Online Article Text |
id | pubmed-8832401 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2021 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-88324012022-02-11 Inorganometallics (Transition Metal–Metalloid Complexes) and Catalysis Marciniec, Bogdan Pietraszuk, Cezary Pawluć, Piotr Maciejewski, Hieronim Chem Rev [Image: see text] While the formation and breaking of transition metal (TM)–carbon bonds plays a pivotal role in the catalysis of organic compounds, the reactivity of inorganometallic species, that is, those involving the transition metal (TM)–metalloid (E) bond, is of key importance in most conversions of metalloid derivatives catalyzed by TM complexes. This Review presents the background of inorganometallic catalysis and its development over the last 15 years. The results of mechanistic studies presented in the Review are related to the occurrence of TM–E and TM–H compounds as reactive intermediates in the catalytic transformations of selected metalloids (E = B, Si, Ge, Sn, As, Sb, or Te). The Review illustrates the significance of inorganometallics in catalysis of the following processes: addition of metalloid–hydrogen and metalloid–metalloid bonds to unsaturated compounds; activation and functionalization of C–H bonds and C–X bonds with hydrometalloids and bismetalloids; activation and functionalization of C–H bonds with vinylmetalloids, metalloid halides, and sulfonates; and dehydrocoupling of hydrometalloids. This first Review on inorganometallic catalysis sums up the developments in the catalytic methods for the synthesis of organometalloid compounds and their applications in advanced organic synthesis as a part of tandem reactions. American Chemical Society 2021-12-30 2022-02-09 /pmc/articles/PMC8832401/ /pubmed/34967210 http://dx.doi.org/10.1021/acs.chemrev.1c00417 Text en © 2021 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Marciniec, Bogdan Pietraszuk, Cezary Pawluć, Piotr Maciejewski, Hieronim Inorganometallics (Transition Metal–Metalloid Complexes) and Catalysis |
title | Inorganometallics (Transition Metal–Metalloid
Complexes) and Catalysis |
title_full | Inorganometallics (Transition Metal–Metalloid
Complexes) and Catalysis |
title_fullStr | Inorganometallics (Transition Metal–Metalloid
Complexes) and Catalysis |
title_full_unstemmed | Inorganometallics (Transition Metal–Metalloid
Complexes) and Catalysis |
title_short | Inorganometallics (Transition Metal–Metalloid
Complexes) and Catalysis |
title_sort | inorganometallics (transition metal–metalloid
complexes) and catalysis |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8832401/ https://www.ncbi.nlm.nih.gov/pubmed/34967210 http://dx.doi.org/10.1021/acs.chemrev.1c00417 |
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