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Structural, Electronic, and Physical Properties of a New Layered Cr-Based Oxyarsenide Sr(2)Cr(2)AsO(3)
We report synthesis, crystal structure, and physical properties of Sr [Formula: see text] Cr [Formula: see text] AsO [Formula: see text] . The new compound crystallizes in a Sr [Formula: see text] GaO [Formula: see text] CuS-type structure with two distinct Cr sites, Cr(1) in the perovskite-like blo...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8836719/ https://www.ncbi.nlm.nih.gov/pubmed/35160747 http://dx.doi.org/10.3390/ma15030802 |
Sumario: | We report synthesis, crystal structure, and physical properties of Sr [Formula: see text] Cr [Formula: see text] AsO [Formula: see text] . The new compound crystallizes in a Sr [Formula: see text] GaO [Formula: see text] CuS-type structure with two distinct Cr sites, Cr(1) in the perovskite-like block layers of “Sr [Formula: see text] Cr [Formula: see text] O [Formula: see text] ” and Cr(2) in the ThCr [Formula: see text] Si [Formula: see text] -type layers of “SrCr [Formula: see text] As [Formula: see text] ”. An inter-block-layer charge transfer is explicitly evidenced, which dopes electrons in the CrO [Formula: see text] planes and simultaneously dopes holes into the CrAs layers. Measurements of electrical resistivity, magnetization, and specific heat, in combination with density-functional theoretical calculations, indicate that the title material is an antiferromagnetic metal. The Cr(2) magnetic moments in the CrAs layers order at 420 K, while the Cr(1) spins in the CrO [Formula: see text] planes show quasi-two-dimensional magnetism with long-range ordering below 80 K. Both Néel temperatures are significantly reduced, compared with those of the cousin material Sr [Formula: see text] Cr [Formula: see text] As [Formula: see text] O [Formula: see text] , probably due to the intrinsic charge-carrier doping. Complex re-entrant magnetic transitions with a huge magnetic hysteresis were observed at low temperatures. |
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