One-Step Synthesis of High Pure Tris(8-hydroxyquinoline)aluminum for Optics and Photonics

A simple method of synthesis of high pure tris(8-hydroxyquinoline)aluminum (Alq(3)) from commercial available 5N Al(2)O(3) and 8-hydroxyquinolinol has been developed. One-step exchange chemical reaction has been conducted under controlled 8-hydrixyquinoline vapor at a temperature of 190–240 °C with...

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Detalles Bibliográficos
Autores principales: Avetisov, Roman, Kazmina, Ksenya, Barkanov, Artem, Zykova, Marina, Khomyakov, Andrew, Pytchenko, Alexander, Avetissov, Igor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8837004/
https://www.ncbi.nlm.nih.gov/pubmed/35160680
http://dx.doi.org/10.3390/ma15030734
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author Avetisov, Roman
Kazmina, Ksenya
Barkanov, Artem
Zykova, Marina
Khomyakov, Andrew
Pytchenko, Alexander
Avetissov, Igor
author_facet Avetisov, Roman
Kazmina, Ksenya
Barkanov, Artem
Zykova, Marina
Khomyakov, Andrew
Pytchenko, Alexander
Avetissov, Igor
author_sort Avetisov, Roman
collection PubMed
description A simple method of synthesis of high pure tris(8-hydroxyquinoline)aluminum (Alq(3)) from commercial available 5N Al(2)O(3) and 8-hydroxyquinolinol has been developed. One-step exchange chemical reaction has been conducted under controlled 8-hydrixyquinoline vapor at a temperature of 190–240 °C with water removal by phosphorus anhydride. According to analysis of inductively coupled plasma mass-spectrometry, the chemical purity of synthesized Alq(3) was 99.998 wt%. Photoluminescence of the synthesized Alq(3) has been measured and slightly differed from those of Alq(3) obtained by traditional organic synthesis.
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spelling pubmed-88370042022-02-12 One-Step Synthesis of High Pure Tris(8-hydroxyquinoline)aluminum for Optics and Photonics Avetisov, Roman Kazmina, Ksenya Barkanov, Artem Zykova, Marina Khomyakov, Andrew Pytchenko, Alexander Avetissov, Igor Materials (Basel) Article A simple method of synthesis of high pure tris(8-hydroxyquinoline)aluminum (Alq(3)) from commercial available 5N Al(2)O(3) and 8-hydroxyquinolinol has been developed. One-step exchange chemical reaction has been conducted under controlled 8-hydrixyquinoline vapor at a temperature of 190–240 °C with water removal by phosphorus anhydride. According to analysis of inductively coupled plasma mass-spectrometry, the chemical purity of synthesized Alq(3) was 99.998 wt%. Photoluminescence of the synthesized Alq(3) has been measured and slightly differed from those of Alq(3) obtained by traditional organic synthesis. MDPI 2022-01-19 /pmc/articles/PMC8837004/ /pubmed/35160680 http://dx.doi.org/10.3390/ma15030734 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Avetisov, Roman
Kazmina, Ksenya
Barkanov, Artem
Zykova, Marina
Khomyakov, Andrew
Pytchenko, Alexander
Avetissov, Igor
One-Step Synthesis of High Pure Tris(8-hydroxyquinoline)aluminum for Optics and Photonics
title One-Step Synthesis of High Pure Tris(8-hydroxyquinoline)aluminum for Optics and Photonics
title_full One-Step Synthesis of High Pure Tris(8-hydroxyquinoline)aluminum for Optics and Photonics
title_fullStr One-Step Synthesis of High Pure Tris(8-hydroxyquinoline)aluminum for Optics and Photonics
title_full_unstemmed One-Step Synthesis of High Pure Tris(8-hydroxyquinoline)aluminum for Optics and Photonics
title_short One-Step Synthesis of High Pure Tris(8-hydroxyquinoline)aluminum for Optics and Photonics
title_sort one-step synthesis of high pure tris(8-hydroxyquinoline)aluminum for optics and photonics
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8837004/
https://www.ncbi.nlm.nih.gov/pubmed/35160680
http://dx.doi.org/10.3390/ma15030734
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