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Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles

In this work, gamma-ray shielding features of crosslinked polystyrene-b-polyethyleneglycol block copolymers (PS-b-PEG) blended with nanostructured selenium dioxide (SeO(2)) and boron nitride (BN) particles were studied. This research details several radiation shielding factors i.e., mass attenuation...

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Autores principales: Cinan, Zehra Merve, Erol, Burcu, Baskan, Taylan, Mutlu, Saliha, Ortaç, Bülend, Savaskan Yilmaz, Sevil, Yilmaz, Ahmet Hakan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8837946/
https://www.ncbi.nlm.nih.gov/pubmed/35159642
http://dx.doi.org/10.3390/nano12030297
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author Cinan, Zehra Merve
Erol, Burcu
Baskan, Taylan
Mutlu, Saliha
Ortaç, Bülend
Savaskan Yilmaz, Sevil
Yilmaz, Ahmet Hakan
author_facet Cinan, Zehra Merve
Erol, Burcu
Baskan, Taylan
Mutlu, Saliha
Ortaç, Bülend
Savaskan Yilmaz, Sevil
Yilmaz, Ahmet Hakan
author_sort Cinan, Zehra Merve
collection PubMed
description In this work, gamma-ray shielding features of crosslinked polystyrene-b-polyethyleneglycol block copolymers (PS-b-PEG) blended with nanostructured selenium dioxide (SeO(2)) and boron nitride (BN) particles were studied. This research details several radiation shielding factors i.e., mass attenuation coefficient ([Formula: see text]), linear attenuation coefficient ([Formula: see text]), radiation protection efficiency (RPE), half-value layer (HVL), tenth-value layer (TVL), and mean free path (MFP). The irradiation properties of our nanocomposites were investigated with rays from the (152)Eu source (in the energy intervals from 121.780 keV to 1408.010 keV) in a high-purity germanium (HPGe) detector system, and analyzed with GammaVision software. Moreover, all radiation shielding factors were determined by theoretical calculus and compared with the experimental results. In addition, the morphological and thermal characterization of all nanocomposites was surveyed with various techniques i.e., nuclear magnetic resonance (NMR), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM). Acceptable compatibility was revealed and observed in all nanocomposites between the experimental and theoretical results. The PS-b-PEG copolymer and nanostructured SeO(2) and BN particles exerted a significant effect in enhancing the resistance of the nanocomposites, and the samples with high additive rates exhibited better resistance than the other nanocomposites. From the achieved outcomes, it can be deduced that our polymer-based nanocomposites can be utilized as a good choice in the gamma-irradiation-shielding discipline.
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spelling pubmed-88379462022-02-13 Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles Cinan, Zehra Merve Erol, Burcu Baskan, Taylan Mutlu, Saliha Ortaç, Bülend Savaskan Yilmaz, Sevil Yilmaz, Ahmet Hakan Nanomaterials (Basel) Article In this work, gamma-ray shielding features of crosslinked polystyrene-b-polyethyleneglycol block copolymers (PS-b-PEG) blended with nanostructured selenium dioxide (SeO(2)) and boron nitride (BN) particles were studied. This research details several radiation shielding factors i.e., mass attenuation coefficient ([Formula: see text]), linear attenuation coefficient ([Formula: see text]), radiation protection efficiency (RPE), half-value layer (HVL), tenth-value layer (TVL), and mean free path (MFP). The irradiation properties of our nanocomposites were investigated with rays from the (152)Eu source (in the energy intervals from 121.780 keV to 1408.010 keV) in a high-purity germanium (HPGe) detector system, and analyzed with GammaVision software. Moreover, all radiation shielding factors were determined by theoretical calculus and compared with the experimental results. In addition, the morphological and thermal characterization of all nanocomposites was surveyed with various techniques i.e., nuclear magnetic resonance (NMR), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM). Acceptable compatibility was revealed and observed in all nanocomposites between the experimental and theoretical results. The PS-b-PEG copolymer and nanostructured SeO(2) and BN particles exerted a significant effect in enhancing the resistance of the nanocomposites, and the samples with high additive rates exhibited better resistance than the other nanocomposites. From the achieved outcomes, it can be deduced that our polymer-based nanocomposites can be utilized as a good choice in the gamma-irradiation-shielding discipline. MDPI 2022-01-18 /pmc/articles/PMC8837946/ /pubmed/35159642 http://dx.doi.org/10.3390/nano12030297 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Cinan, Zehra Merve
Erol, Burcu
Baskan, Taylan
Mutlu, Saliha
Ortaç, Bülend
Savaskan Yilmaz, Sevil
Yilmaz, Ahmet Hakan
Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles
title Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles
title_full Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles
title_fullStr Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles
title_full_unstemmed Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles
title_short Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles
title_sort radiation shielding tests of crosslinked polystyrene-b-polyethyleneglycol block copolymers blended with nanostructured selenium dioxide and boron nitride particles
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8837946/
https://www.ncbi.nlm.nih.gov/pubmed/35159642
http://dx.doi.org/10.3390/nano12030297
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