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Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles
In this work, gamma-ray shielding features of crosslinked polystyrene-b-polyethyleneglycol block copolymers (PS-b-PEG) blended with nanostructured selenium dioxide (SeO(2)) and boron nitride (BN) particles were studied. This research details several radiation shielding factors i.e., mass attenuation...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8837946/ https://www.ncbi.nlm.nih.gov/pubmed/35159642 http://dx.doi.org/10.3390/nano12030297 |
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author | Cinan, Zehra Merve Erol, Burcu Baskan, Taylan Mutlu, Saliha Ortaç, Bülend Savaskan Yilmaz, Sevil Yilmaz, Ahmet Hakan |
author_facet | Cinan, Zehra Merve Erol, Burcu Baskan, Taylan Mutlu, Saliha Ortaç, Bülend Savaskan Yilmaz, Sevil Yilmaz, Ahmet Hakan |
author_sort | Cinan, Zehra Merve |
collection | PubMed |
description | In this work, gamma-ray shielding features of crosslinked polystyrene-b-polyethyleneglycol block copolymers (PS-b-PEG) blended with nanostructured selenium dioxide (SeO(2)) and boron nitride (BN) particles were studied. This research details several radiation shielding factors i.e., mass attenuation coefficient ([Formula: see text]), linear attenuation coefficient ([Formula: see text]), radiation protection efficiency (RPE), half-value layer (HVL), tenth-value layer (TVL), and mean free path (MFP). The irradiation properties of our nanocomposites were investigated with rays from the (152)Eu source (in the energy intervals from 121.780 keV to 1408.010 keV) in a high-purity germanium (HPGe) detector system, and analyzed with GammaVision software. Moreover, all radiation shielding factors were determined by theoretical calculus and compared with the experimental results. In addition, the morphological and thermal characterization of all nanocomposites was surveyed with various techniques i.e., nuclear magnetic resonance (NMR), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM). Acceptable compatibility was revealed and observed in all nanocomposites between the experimental and theoretical results. The PS-b-PEG copolymer and nanostructured SeO(2) and BN particles exerted a significant effect in enhancing the resistance of the nanocomposites, and the samples with high additive rates exhibited better resistance than the other nanocomposites. From the achieved outcomes, it can be deduced that our polymer-based nanocomposites can be utilized as a good choice in the gamma-irradiation-shielding discipline. |
format | Online Article Text |
id | pubmed-8837946 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-88379462022-02-13 Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles Cinan, Zehra Merve Erol, Burcu Baskan, Taylan Mutlu, Saliha Ortaç, Bülend Savaskan Yilmaz, Sevil Yilmaz, Ahmet Hakan Nanomaterials (Basel) Article In this work, gamma-ray shielding features of crosslinked polystyrene-b-polyethyleneglycol block copolymers (PS-b-PEG) blended with nanostructured selenium dioxide (SeO(2)) and boron nitride (BN) particles were studied. This research details several radiation shielding factors i.e., mass attenuation coefficient ([Formula: see text]), linear attenuation coefficient ([Formula: see text]), radiation protection efficiency (RPE), half-value layer (HVL), tenth-value layer (TVL), and mean free path (MFP). The irradiation properties of our nanocomposites were investigated with rays from the (152)Eu source (in the energy intervals from 121.780 keV to 1408.010 keV) in a high-purity germanium (HPGe) detector system, and analyzed with GammaVision software. Moreover, all radiation shielding factors were determined by theoretical calculus and compared with the experimental results. In addition, the morphological and thermal characterization of all nanocomposites was surveyed with various techniques i.e., nuclear magnetic resonance (NMR), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and transmission electron microscopy (TEM). Acceptable compatibility was revealed and observed in all nanocomposites between the experimental and theoretical results. The PS-b-PEG copolymer and nanostructured SeO(2) and BN particles exerted a significant effect in enhancing the resistance of the nanocomposites, and the samples with high additive rates exhibited better resistance than the other nanocomposites. From the achieved outcomes, it can be deduced that our polymer-based nanocomposites can be utilized as a good choice in the gamma-irradiation-shielding discipline. MDPI 2022-01-18 /pmc/articles/PMC8837946/ /pubmed/35159642 http://dx.doi.org/10.3390/nano12030297 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Cinan, Zehra Merve Erol, Burcu Baskan, Taylan Mutlu, Saliha Ortaç, Bülend Savaskan Yilmaz, Sevil Yilmaz, Ahmet Hakan Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles |
title | Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles |
title_full | Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles |
title_fullStr | Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles |
title_full_unstemmed | Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles |
title_short | Radiation Shielding Tests of Crosslinked Polystyrene-b-Polyethyleneglycol Block Copolymers Blended with Nanostructured Selenium Dioxide and Boron Nitride Particles |
title_sort | radiation shielding tests of crosslinked polystyrene-b-polyethyleneglycol block copolymers blended with nanostructured selenium dioxide and boron nitride particles |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8837946/ https://www.ncbi.nlm.nih.gov/pubmed/35159642 http://dx.doi.org/10.3390/nano12030297 |
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