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Fabrication, Characterization and Evaluation of an Alginate–Lignin Composite for Rare-Earth Elements Recovery
The recent increase in interest in rare earth elements is due to their increasing use in many areas of life. However, along with their increasing popularity, the problem of their natural resources availability arises. In this study, an alginate–lignin composite (ALG-L) was fabricated and tested for...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8838038/ https://www.ncbi.nlm.nih.gov/pubmed/35160907 http://dx.doi.org/10.3390/ma15030944 |
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author | Fila, Dominika Hubicki, Zbigniew Kołodyńska, Dorota |
author_facet | Fila, Dominika Hubicki, Zbigniew Kołodyńska, Dorota |
author_sort | Fila, Dominika |
collection | PubMed |
description | The recent increase in interest in rare earth elements is due to their increasing use in many areas of life. However, along with their increasing popularity, the problem of their natural resources availability arises. In this study, an alginate–lignin composite (ALG-L) was fabricated and tested for adsorptive abilities of the rare earth elements (La(III), Ce(III), Pr(III), and Nd(III)) from aqueous solutions. The characterization of the newly synthetized calcium alginate–lignin composite was performed using ATR/FT-IR, SEM, EDX, OM, AFM, XRD, BET, sieve analysis and pH(pzc) measurements. The adsorption mechanism of the ALG(5)L(1) composite for REEs was analyzed through a series of kinetic, equilibrium and thermodynamic adsorption experiments. Under the optimum sorption conditions, i.e., sorbent mass 0.1 g, pH 5.0, temperature 333 K, the maximum adsorption capacities of the ALG(5)L(1) composite for La(III), Ce(III), Pr(III), and Nd(III) reached 109.56, 97.97, 97.98, and 98.68 mg/g, respectively. The desorption studies indicate that the new calcium alginate–lignin composite is characterized by good recycling properties and can be also reused. To sum up the advantages of low cost, easy synthesis, high adsorption efficiencies and reusability indicate that the ALG(5)L(1) composite has great application perspectives for REEs recovery. |
format | Online Article Text |
id | pubmed-8838038 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-88380382022-02-13 Fabrication, Characterization and Evaluation of an Alginate–Lignin Composite for Rare-Earth Elements Recovery Fila, Dominika Hubicki, Zbigniew Kołodyńska, Dorota Materials (Basel) Article The recent increase in interest in rare earth elements is due to their increasing use in many areas of life. However, along with their increasing popularity, the problem of their natural resources availability arises. In this study, an alginate–lignin composite (ALG-L) was fabricated and tested for adsorptive abilities of the rare earth elements (La(III), Ce(III), Pr(III), and Nd(III)) from aqueous solutions. The characterization of the newly synthetized calcium alginate–lignin composite was performed using ATR/FT-IR, SEM, EDX, OM, AFM, XRD, BET, sieve analysis and pH(pzc) measurements. The adsorption mechanism of the ALG(5)L(1) composite for REEs was analyzed through a series of kinetic, equilibrium and thermodynamic adsorption experiments. Under the optimum sorption conditions, i.e., sorbent mass 0.1 g, pH 5.0, temperature 333 K, the maximum adsorption capacities of the ALG(5)L(1) composite for La(III), Ce(III), Pr(III), and Nd(III) reached 109.56, 97.97, 97.98, and 98.68 mg/g, respectively. The desorption studies indicate that the new calcium alginate–lignin composite is characterized by good recycling properties and can be also reused. To sum up the advantages of low cost, easy synthesis, high adsorption efficiencies and reusability indicate that the ALG(5)L(1) composite has great application perspectives for REEs recovery. MDPI 2022-01-26 /pmc/articles/PMC8838038/ /pubmed/35160907 http://dx.doi.org/10.3390/ma15030944 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Fila, Dominika Hubicki, Zbigniew Kołodyńska, Dorota Fabrication, Characterization and Evaluation of an Alginate–Lignin Composite for Rare-Earth Elements Recovery |
title | Fabrication, Characterization and Evaluation of an Alginate–Lignin Composite for Rare-Earth Elements Recovery |
title_full | Fabrication, Characterization and Evaluation of an Alginate–Lignin Composite for Rare-Earth Elements Recovery |
title_fullStr | Fabrication, Characterization and Evaluation of an Alginate–Lignin Composite for Rare-Earth Elements Recovery |
title_full_unstemmed | Fabrication, Characterization and Evaluation of an Alginate–Lignin Composite for Rare-Earth Elements Recovery |
title_short | Fabrication, Characterization and Evaluation of an Alginate–Lignin Composite for Rare-Earth Elements Recovery |
title_sort | fabrication, characterization and evaluation of an alginate–lignin composite for rare-earth elements recovery |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8838038/ https://www.ncbi.nlm.nih.gov/pubmed/35160907 http://dx.doi.org/10.3390/ma15030944 |
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