Cargando…

As((III, V)) Uptake from Nanostructured Iron Oxides and Oxyhydroxides: The Complex Interplay between Sorbent Surface Chemistry and Arsenic Equilibria

Iron oxides/oxyhydroxides, namely maghemite, iron oxide-silica composite, akaganeite, and ferrihydrite, are studied for As(V) and As(III) removal from water in the pH range 2–8. All sorbents were characterized for their structural, morphological, textural, and surface charge properties. The same exp...

Descripción completa

Detalles Bibliográficos
Autores principales: Sanna Angotzi, Marco, Mameli, Valentina, Fantasia, Alessandra, Cara, Claudio, Secci, Fausto, Enzo, Stefano, Gerina, Marianna, Cannas, Carla
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8840107/
https://www.ncbi.nlm.nih.gov/pubmed/35159671
http://dx.doi.org/10.3390/nano12030326
_version_ 1784650536885157888
author Sanna Angotzi, Marco
Mameli, Valentina
Fantasia, Alessandra
Cara, Claudio
Secci, Fausto
Enzo, Stefano
Gerina, Marianna
Cannas, Carla
author_facet Sanna Angotzi, Marco
Mameli, Valentina
Fantasia, Alessandra
Cara, Claudio
Secci, Fausto
Enzo, Stefano
Gerina, Marianna
Cannas, Carla
author_sort Sanna Angotzi, Marco
collection PubMed
description Iron oxides/oxyhydroxides, namely maghemite, iron oxide-silica composite, akaganeite, and ferrihydrite, are studied for As(V) and As(III) removal from water in the pH range 2–8. All sorbents were characterized for their structural, morphological, textural, and surface charge properties. The same experimental conditions for the batch tests permitted a direct comparison among the sorbents, particularly between the oxyhydroxides, known to be among the most promising As-removers but hardly compared in the literature. The tests revealed akaganeite to perform better in the whole pH range for As(V) (max 89 mg g(−1) at pH(0) 3) but to be also efficient toward As(III) (max 91 mg g(−1) at pH(0) 3–8), for which the best sorbent was ferrihydrite (max 144 mg g(−1) at pH(0) 8). Moreover, the study of the sorbents’ surface chemistry under contact with arsenic and arsenic-free solutions allowed the understanding of its role in the arsenic uptake through electrophoretic light scattering and pH measurements. Indeed, the sorbent’s ability to modify the starting pH was a crucial step in determining the removal of performances. The As(V) initial concentration, contact time, ionic strength, and presence of competitors were also studied for akaganeite, the most promising remover, at pH(0) 3 and 8 to deepen the uptake mechanism.
format Online
Article
Text
id pubmed-8840107
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-88401072022-02-13 As((III, V)) Uptake from Nanostructured Iron Oxides and Oxyhydroxides: The Complex Interplay between Sorbent Surface Chemistry and Arsenic Equilibria Sanna Angotzi, Marco Mameli, Valentina Fantasia, Alessandra Cara, Claudio Secci, Fausto Enzo, Stefano Gerina, Marianna Cannas, Carla Nanomaterials (Basel) Article Iron oxides/oxyhydroxides, namely maghemite, iron oxide-silica composite, akaganeite, and ferrihydrite, are studied for As(V) and As(III) removal from water in the pH range 2–8. All sorbents were characterized for their structural, morphological, textural, and surface charge properties. The same experimental conditions for the batch tests permitted a direct comparison among the sorbents, particularly between the oxyhydroxides, known to be among the most promising As-removers but hardly compared in the literature. The tests revealed akaganeite to perform better in the whole pH range for As(V) (max 89 mg g(−1) at pH(0) 3) but to be also efficient toward As(III) (max 91 mg g(−1) at pH(0) 3–8), for which the best sorbent was ferrihydrite (max 144 mg g(−1) at pH(0) 8). Moreover, the study of the sorbents’ surface chemistry under contact with arsenic and arsenic-free solutions allowed the understanding of its role in the arsenic uptake through electrophoretic light scattering and pH measurements. Indeed, the sorbent’s ability to modify the starting pH was a crucial step in determining the removal of performances. The As(V) initial concentration, contact time, ionic strength, and presence of competitors were also studied for akaganeite, the most promising remover, at pH(0) 3 and 8 to deepen the uptake mechanism. MDPI 2022-01-20 /pmc/articles/PMC8840107/ /pubmed/35159671 http://dx.doi.org/10.3390/nano12030326 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Sanna Angotzi, Marco
Mameli, Valentina
Fantasia, Alessandra
Cara, Claudio
Secci, Fausto
Enzo, Stefano
Gerina, Marianna
Cannas, Carla
As((III, V)) Uptake from Nanostructured Iron Oxides and Oxyhydroxides: The Complex Interplay between Sorbent Surface Chemistry and Arsenic Equilibria
title As((III, V)) Uptake from Nanostructured Iron Oxides and Oxyhydroxides: The Complex Interplay between Sorbent Surface Chemistry and Arsenic Equilibria
title_full As((III, V)) Uptake from Nanostructured Iron Oxides and Oxyhydroxides: The Complex Interplay between Sorbent Surface Chemistry and Arsenic Equilibria
title_fullStr As((III, V)) Uptake from Nanostructured Iron Oxides and Oxyhydroxides: The Complex Interplay between Sorbent Surface Chemistry and Arsenic Equilibria
title_full_unstemmed As((III, V)) Uptake from Nanostructured Iron Oxides and Oxyhydroxides: The Complex Interplay between Sorbent Surface Chemistry and Arsenic Equilibria
title_short As((III, V)) Uptake from Nanostructured Iron Oxides and Oxyhydroxides: The Complex Interplay between Sorbent Surface Chemistry and Arsenic Equilibria
title_sort as((iii, v)) uptake from nanostructured iron oxides and oxyhydroxides: the complex interplay between sorbent surface chemistry and arsenic equilibria
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8840107/
https://www.ncbi.nlm.nih.gov/pubmed/35159671
http://dx.doi.org/10.3390/nano12030326
work_keys_str_mv AT sannaangotzimarco asiiivuptakefromnanostructuredironoxidesandoxyhydroxidesthecomplexinterplaybetweensorbentsurfacechemistryandarsenicequilibria
AT mamelivalentina asiiivuptakefromnanostructuredironoxidesandoxyhydroxidesthecomplexinterplaybetweensorbentsurfacechemistryandarsenicequilibria
AT fantasiaalessandra asiiivuptakefromnanostructuredironoxidesandoxyhydroxidesthecomplexinterplaybetweensorbentsurfacechemistryandarsenicequilibria
AT caraclaudio asiiivuptakefromnanostructuredironoxidesandoxyhydroxidesthecomplexinterplaybetweensorbentsurfacechemistryandarsenicequilibria
AT seccifausto asiiivuptakefromnanostructuredironoxidesandoxyhydroxidesthecomplexinterplaybetweensorbentsurfacechemistryandarsenicequilibria
AT enzostefano asiiivuptakefromnanostructuredironoxidesandoxyhydroxidesthecomplexinterplaybetweensorbentsurfacechemistryandarsenicequilibria
AT gerinamarianna asiiivuptakefromnanostructuredironoxidesandoxyhydroxidesthecomplexinterplaybetweensorbentsurfacechemistryandarsenicequilibria
AT cannascarla asiiivuptakefromnanostructuredironoxidesandoxyhydroxidesthecomplexinterplaybetweensorbentsurfacechemistryandarsenicequilibria