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High-Stability Ti(3)C(2)-QDs/ZnIn(2)S(4)/Ti(IV) Flower-like Heterojunction for Boosted Photocatalytic Hydrogen Evolution
The practical application of photocatalytic H(2)-evolution is greatly limited by its sluggish charge separation, insufficient active sites, and stability of photocatalysts. Zero-dimensional (0D) Ti(3)C(2) MXene quantum dots (MQDs) and amorphous Ti(IV) have been proven to be potential substitutes for...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8840382/ https://www.ncbi.nlm.nih.gov/pubmed/35159887 http://dx.doi.org/10.3390/nano12030542 |
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author | Yang, Liqin Chen, Zhihong Wang, Xin Jin, Mingliang |
author_facet | Yang, Liqin Chen, Zhihong Wang, Xin Jin, Mingliang |
author_sort | Yang, Liqin |
collection | PubMed |
description | The practical application of photocatalytic H(2)-evolution is greatly limited by its sluggish charge separation, insufficient active sites, and stability of photocatalysts. Zero-dimensional (0D) Ti(3)C(2) MXene quantum dots (MQDs) and amorphous Ti(IV) have been proven to be potential substitutes for noble co-catalyst to accelerate the separation of photogenerated electron-hole pairs and prevent the self-oxidation of photocatalysts, leading to better photocatalytic H(2)-evolution performance with long-term stability. In this study, amorphous Ti(IV) and MQDs co-catalysts were successfully deposited on ZnIn(2)S(4) (ZIS) microspheres composed of ultra-thin nanosheets via a simple impregnation and self-assembly method (denoted as MQDs/ZIS/Ti(IV)). As expected, the optimal MQDs/ZIS/Ti(IV) sample exhibited a photocatalytic H(2)-evolution rate of 7.52 mmol·g(−1)·h(−1) and excellent photostability without metallic Pt as the co-catalyst in the presence of Na(2)S/Na(2)SO(3) as hole scavenger, about 16, 4.02 and 4.25 times higher than those of ZIS, ZIS/Ti(IV), and MQDs/ZIS, respectively. The significantly enhanced photocatalytic H(2)-evolution activity is attributed to the synergistic effect of the three-dimensional (3D) flower-like microsphere structure, the amorphous Ti(IV) hole co-catalyst, and a Schottky junction formed at the ZIS–MQDs interface, which offers more active sites, suppresses self-photocorrosion, and photo-generates the charge recombination of ZIS. |
format | Online Article Text |
id | pubmed-8840382 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-88403822022-02-13 High-Stability Ti(3)C(2)-QDs/ZnIn(2)S(4)/Ti(IV) Flower-like Heterojunction for Boosted Photocatalytic Hydrogen Evolution Yang, Liqin Chen, Zhihong Wang, Xin Jin, Mingliang Nanomaterials (Basel) Article The practical application of photocatalytic H(2)-evolution is greatly limited by its sluggish charge separation, insufficient active sites, and stability of photocatalysts. Zero-dimensional (0D) Ti(3)C(2) MXene quantum dots (MQDs) and amorphous Ti(IV) have been proven to be potential substitutes for noble co-catalyst to accelerate the separation of photogenerated electron-hole pairs and prevent the self-oxidation of photocatalysts, leading to better photocatalytic H(2)-evolution performance with long-term stability. In this study, amorphous Ti(IV) and MQDs co-catalysts were successfully deposited on ZnIn(2)S(4) (ZIS) microspheres composed of ultra-thin nanosheets via a simple impregnation and self-assembly method (denoted as MQDs/ZIS/Ti(IV)). As expected, the optimal MQDs/ZIS/Ti(IV) sample exhibited a photocatalytic H(2)-evolution rate of 7.52 mmol·g(−1)·h(−1) and excellent photostability without metallic Pt as the co-catalyst in the presence of Na(2)S/Na(2)SO(3) as hole scavenger, about 16, 4.02 and 4.25 times higher than those of ZIS, ZIS/Ti(IV), and MQDs/ZIS, respectively. The significantly enhanced photocatalytic H(2)-evolution activity is attributed to the synergistic effect of the three-dimensional (3D) flower-like microsphere structure, the amorphous Ti(IV) hole co-catalyst, and a Schottky junction formed at the ZIS–MQDs interface, which offers more active sites, suppresses self-photocorrosion, and photo-generates the charge recombination of ZIS. MDPI 2022-02-05 /pmc/articles/PMC8840382/ /pubmed/35159887 http://dx.doi.org/10.3390/nano12030542 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Yang, Liqin Chen, Zhihong Wang, Xin Jin, Mingliang High-Stability Ti(3)C(2)-QDs/ZnIn(2)S(4)/Ti(IV) Flower-like Heterojunction for Boosted Photocatalytic Hydrogen Evolution |
title | High-Stability Ti(3)C(2)-QDs/ZnIn(2)S(4)/Ti(IV) Flower-like Heterojunction for Boosted Photocatalytic Hydrogen Evolution |
title_full | High-Stability Ti(3)C(2)-QDs/ZnIn(2)S(4)/Ti(IV) Flower-like Heterojunction for Boosted Photocatalytic Hydrogen Evolution |
title_fullStr | High-Stability Ti(3)C(2)-QDs/ZnIn(2)S(4)/Ti(IV) Flower-like Heterojunction for Boosted Photocatalytic Hydrogen Evolution |
title_full_unstemmed | High-Stability Ti(3)C(2)-QDs/ZnIn(2)S(4)/Ti(IV) Flower-like Heterojunction for Boosted Photocatalytic Hydrogen Evolution |
title_short | High-Stability Ti(3)C(2)-QDs/ZnIn(2)S(4)/Ti(IV) Flower-like Heterojunction for Boosted Photocatalytic Hydrogen Evolution |
title_sort | high-stability ti(3)c(2)-qds/znin(2)s(4)/ti(iv) flower-like heterojunction for boosted photocatalytic hydrogen evolution |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8840382/ https://www.ncbi.nlm.nih.gov/pubmed/35159887 http://dx.doi.org/10.3390/nano12030542 |
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