In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol

Exploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hy...

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Detalles Bibliográficos
Autores principales: Bruna, Lauriane, Cardona-Farreny, Miquel, Colliere, Vincent, Philippot, Karine, Axet, M. Rosa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8840484/
https://www.ncbi.nlm.nih.gov/pubmed/35159673
http://dx.doi.org/10.3390/nano12030328
Descripción
Sumario:Exploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hydrogenation/C-O cleavage procedure. Colloidal ruthenium nanoparticles stabilized with polyvinylpyrrolidone in situ modified with different organic compounds are able to produce 1,2-pentanediol directly from furfural in a 36% of selectivity at 125 °C under 20 bar of H(2) pressure.

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