In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol

Exploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hy...

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Autores principales: Bruna, Lauriane, Cardona-Farreny, Miquel, Colliere, Vincent, Philippot, Karine, Axet, M. Rosa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8840484/
https://www.ncbi.nlm.nih.gov/pubmed/35159673
http://dx.doi.org/10.3390/nano12030328
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author Bruna, Lauriane
Cardona-Farreny, Miquel
Colliere, Vincent
Philippot, Karine
Axet, M. Rosa
author_facet Bruna, Lauriane
Cardona-Farreny, Miquel
Colliere, Vincent
Philippot, Karine
Axet, M. Rosa
author_sort Bruna, Lauriane
collection PubMed
description Exploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hydrogenation/C-O cleavage procedure. Colloidal ruthenium nanoparticles stabilized with polyvinylpyrrolidone in situ modified with different organic compounds are able to produce 1,2-pentanediol directly from furfural in a 36% of selectivity at 125 °C under 20 bar of H(2) pressure.
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spelling pubmed-88404842022-02-13 In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol Bruna, Lauriane Cardona-Farreny, Miquel Colliere, Vincent Philippot, Karine Axet, M. Rosa Nanomaterials (Basel) Article Exploiting biomass to synthesise compounds that may replace fossil-based ones is of high interest in order to reduce dependence on non-renewable resources. 1,2-pentanediol and 1,5-pentanediol can be produced from furfural, furfuryl alcohol or tetrahydrofurfuryl alcohol following a metal catalysed hydrogenation/C-O cleavage procedure. Colloidal ruthenium nanoparticles stabilized with polyvinylpyrrolidone in situ modified with different organic compounds are able to produce 1,2-pentanediol directly from furfural in a 36% of selectivity at 125 °C under 20 bar of H(2) pressure. MDPI 2022-01-20 /pmc/articles/PMC8840484/ /pubmed/35159673 http://dx.doi.org/10.3390/nano12030328 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Bruna, Lauriane
Cardona-Farreny, Miquel
Colliere, Vincent
Philippot, Karine
Axet, M. Rosa
In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol
title In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol
title_full In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol
title_fullStr In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol
title_full_unstemmed In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol
title_short In Situ Ruthenium Catalyst Modification for the Conversion of Furfural to 1,2-Pentanediol
title_sort in situ ruthenium catalyst modification for the conversion of furfural to 1,2-pentanediol
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8840484/
https://www.ncbi.nlm.nih.gov/pubmed/35159673
http://dx.doi.org/10.3390/nano12030328
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