Phosphine-Catalyzed Dearomative [3 + 2] Cycloaddition of Benzoxazoles with a Cyclopropenone

[Image: see text] The triphenylphosphine-catalyzed dearomative [3 + 2] cycloaddition of benzoxazoles with 1,2-diphenylcyclopropenone is herein described. The reaction scope, mechanism, and possible future applications of this rare organocatalyzed cycloaddition are herein discussed.

Detalles Bibliográficos
Autores principales: Wang, Xingben, Yu, Congjun, Atodiresei, Iuliana L., Patureau, Frederic W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8845044/
https://www.ncbi.nlm.nih.gov/pubmed/35085442
http://dx.doi.org/10.1021/acs.orglett.1c04045
Descripción
Sumario:[Image: see text] The triphenylphosphine-catalyzed dearomative [3 + 2] cycloaddition of benzoxazoles with 1,2-diphenylcyclopropenone is herein described. The reaction scope, mechanism, and possible future applications of this rare organocatalyzed cycloaddition are herein discussed.

Ejemplares similares