Phosphine-Catalyzed Dearomative [3 + 2] Cycloaddition of Benzoxazoles with a Cyclopropenone

[Image: see text] The triphenylphosphine-catalyzed dearomative [3 + 2] cycloaddition of benzoxazoles with 1,2-diphenylcyclopropenone is herein described. The reaction scope, mechanism, and possible future applications of this rare organocatalyzed cycloaddition are herein discussed.

Detalles Bibliográficos
Autores principales: Wang, Xingben, Yu, Congjun, Atodiresei, Iuliana L., Patureau, Frederic W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8845044/
https://www.ncbi.nlm.nih.gov/pubmed/35085442
http://dx.doi.org/10.1021/acs.orglett.1c04045
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author Wang, Xingben
Yu, Congjun
Atodiresei, Iuliana L.
Patureau, Frederic W.
author_facet Wang, Xingben
Yu, Congjun
Atodiresei, Iuliana L.
Patureau, Frederic W.
author_sort Wang, Xingben
collection PubMed
description [Image: see text] The triphenylphosphine-catalyzed dearomative [3 + 2] cycloaddition of benzoxazoles with 1,2-diphenylcyclopropenone is herein described. The reaction scope, mechanism, and possible future applications of this rare organocatalyzed cycloaddition are herein discussed.
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spelling pubmed-88450442022-02-15 Phosphine-Catalyzed Dearomative [3 + 2] Cycloaddition of Benzoxazoles with a Cyclopropenone Wang, Xingben Yu, Congjun Atodiresei, Iuliana L. Patureau, Frederic W. Org Lett [Image: see text] The triphenylphosphine-catalyzed dearomative [3 + 2] cycloaddition of benzoxazoles with 1,2-diphenylcyclopropenone is herein described. The reaction scope, mechanism, and possible future applications of this rare organocatalyzed cycloaddition are herein discussed. American Chemical Society 2022-01-27 2022-02-11 /pmc/articles/PMC8845044/ /pubmed/35085442 http://dx.doi.org/10.1021/acs.orglett.1c04045 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Wang, Xingben
Yu, Congjun
Atodiresei, Iuliana L.
Patureau, Frederic W.
Phosphine-Catalyzed Dearomative [3 + 2] Cycloaddition of Benzoxazoles with a Cyclopropenone
title Phosphine-Catalyzed Dearomative [3 + 2] Cycloaddition of Benzoxazoles with a Cyclopropenone
title_full Phosphine-Catalyzed Dearomative [3 + 2] Cycloaddition of Benzoxazoles with a Cyclopropenone
title_fullStr Phosphine-Catalyzed Dearomative [3 + 2] Cycloaddition of Benzoxazoles with a Cyclopropenone
title_full_unstemmed Phosphine-Catalyzed Dearomative [3 + 2] Cycloaddition of Benzoxazoles with a Cyclopropenone
title_short Phosphine-Catalyzed Dearomative [3 + 2] Cycloaddition of Benzoxazoles with a Cyclopropenone
title_sort phosphine-catalyzed dearomative [3 + 2] cycloaddition of benzoxazoles with a cyclopropenone
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8845044/
https://www.ncbi.nlm.nih.gov/pubmed/35085442
http://dx.doi.org/10.1021/acs.orglett.1c04045
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AT atodireseiiulianal phosphinecatalyzeddearomative32cycloadditionofbenzoxazoleswithacyclopropenone
AT patureaufredericw phosphinecatalyzeddearomative32cycloadditionofbenzoxazoleswithacyclopropenone

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