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A BINOL-phosphoric acid and metalloporphyrin derived chiral covalent organic framework for enantioselective α-benzylation of aldehydes

The catalytic asymmetric α-benzylation of aldehydes represents a highly valuable reaction for organic synthesis. For example, the generated α-heteroarylmethyl aldehydes, such as (R)-2-methyl-3-(pyridin-4-yl)propanal ((R)-MPP), are an important class of synthons to access bioactive drugs and natural...

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Detalles Bibliográficos
Autores principales:	Ma, Hui-Chao, Sun, Ya-Nan, Chen, Gong-Jun, Dong, Yu-Bin
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8848806/ https://www.ncbi.nlm.nih.gov/pubmed/35308838 http://dx.doi.org/10.1039/d1sc06045g

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