Enantioselective one-carbon expansion of aromatic rings by simultaneous formation and chromoselective irradiation of a transient coloured enolate

Enantioenriched seven-membered carbocycles are motifs in many molecules of structural and biological interest. We report a simple, practical, transition metal-free and mechanistically unusual method for the enantioselective synthesis of substituted cycloheptatrienes. By forming a coloured enolate wi...

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Detalles Bibliográficos
Autores principales: Saunthwal, Rakesh K., Mortimer, James, Orr-Ewing, Andrew J., Clayden, Jonathan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8848985/
https://www.ncbi.nlm.nih.gov/pubmed/35308841
http://dx.doi.org/10.1039/d1sc06684f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8848985/
https://www.ncbi.nlm.nih.gov/pubmed/35308841
http://dx.doi.org/10.1039/d1sc06684f

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