Cargando…

Practical synthesis of 3-aryl anthranils via an electrophilic aromatic substitution strategy

We report a practical route for the synthesis of valuable 3-aryl anthranils from readily available anthranils and simple arenes by using the classical electrophilic aromatic substitution (EAS) strategy. This transformation goes through an electrophilic substitution and rearomatisation sequence by em...

Descripción completa

Detalles Bibliográficos
Autores principales:	Gao, Yang, Yang, Simin, She, Minwei, Nie, Jianhong, Huo, Yanping, Chen, Qian, Li, Xianwei, Hu, Xiao-Qiang
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8849043/ https://www.ncbi.nlm.nih.gov/pubmed/35308846 http://dx.doi.org/10.1039/d1sc06565c

Ejemplares similares

Energetics of Electron Pairs in Electrophilic Aromatic Substitutions
por: Munárriz, Julen, et al.
Publicado: (2021)

Cobalt-Catalyzed Electrophilic Aminations with Anthranils: An Expedient Route to Condensed Quinolines
por: Li, Jie, et al.
Publicado: (2018)

Fast and accurate prediction of the regioselectivity of electrophilic aromatic substitution reactions
por: Kromann, Jimmy C., et al.
Publicado: (2017)

Prediction of the Synthesis of Spiro Derivatives by Double Intramolecular Aromatic Electrophilic Substitution Using Reactivity Indices
por: Dalinot, Clément, et al.
Publicado: (2019)

Precise through-space control of an abiotic electrophilic aromatic substitution reaction
por: Murphy, Kyle E., et al.
Publicado: (2017)

RegioSQM20: improved prediction of the regioselectivity of electrophilic aromatic substitutions
por: Ree, Nicolai, et al.
Publicado: (2021)

Hydrazinosulfonylation of aryl electrophiles: a straightforward approach for the synthesis of aryl N-aminosulfonamides
por: Hsu, Chou-Yi, et al.
Publicado: (2023)

Polymer-supported synthesis of N-substituted anthranilates as the building blocks for preparation of N-arylated 3-hydroxyquinolin-4(1H)-ones
por: Krajčovičová, Soňa, et al.
Publicado: (2021)

High Site Selectivity in Electrophilic Aromatic Substitutions: Mechanism of C–H Thianthrenation
por: Juliá, Fabio, et al.
Publicado: (2021)

Mechanistic Characterization of Zeolite-Catalyzed Aromatic Electrophilic Substitution at Realistic Operating Conditions
por: Bocus, Massimo, et al.
Publicado: (2022)

A Lewis Acid Stabilized Ketenimine in an Unusual Variant of the Electrophilic Aromatic Substitution
por: Surkau, Jonas, et al.
Publicado: (2022)

Synthesis of 1-Silabenzo[d,e]isochromanes via Electrophilic Aromatic Substitution of Aldehydes Activated by Silylium Ion
por: Arii, Hidekazu, et al.
Publicado: (2022)

Hypervalent iodine-guided electrophilic substitution: para-selective substitution across aryl iodonium compounds with benzyl groups
por: Mowdawalla, Cyrus, et al.
Publicado: (2018)

A versatile route to edge-specific modifications to pristine graphene by electrophilic aromatic substitution
por: Shellard, Philippa M., et al.
Publicado: (2020)

Glucosyl anthranilate
por: Liu, Haoyan, et al.
Publicado: (2009)

Synthesis of Functional Fluorescent BODIPY‐based Dyes through Electrophilic Aromatic Substitution: Straightforward Approach towards Customized Fluorescent Probes
por: Mirri, Giorgio, et al.
Publicado: (2016)

Synthesis and kinetic resolution of substituted tetrahydroquinolines by lithiation then electrophilic quench
por: Carter, Nicholas, et al.
Publicado: (2017)

Anthranilic acid, the new player in the ensemble of aromatic residue labeling precursor compounds
por: Schörghuber, Julia, et al.
Publicado: (2017)

Engineering of Saccharomyces cerevisiae for anthranilate and methyl anthranilate production
por: Kuivanen, Joosu, et al.
Publicado: (2021)

Synthesis and Electrophilic Substitution of Pyrido[2,3,4-kl]- acridines‡
por: Koller, Avi, et al.
Publicado: (2001)

Desulfination by 2′-hydroxybiphenyl-2-sulfinate desulfinase proceeds via electrophilic aromatic substitution by the cysteine-27 proton
por: Geronimo, Inacrist, et al.
Publicado: (2017)

Analogy of the Reactions of Aromatic and Aliphatic π-Electrophiles with Nucleophiles
por: Barbasiewicz, Michał, et al.
Publicado: (2023)

Stereoconvergent Arylations and Alkenylations of Unactivated Alkyl Electrophiles: Catalytic Enantioselective Synthesis of Secondary Sulfonamides and Sulfones
por: Choi, Junwon, et al.
Publicado: (2014)

Synthesis of metal anthranilate complexes: catalytic and antipathogenic studies
por: Nawaz, Muhammad, et al.
Publicado: (2022)

Enantioselective alkylative cross-coupling of unactivated aromatic C–O electrophiles
por: Zhang, Zishuo, et al.
Publicado: (2022)

Investigation into the Semantic Density and Semantic Gravity Wave Profile of Teachers When Discussing Electrophilic Aromatic Substitution (S(E)Ar)
por: Cranwell, Philippa B., et al.
Publicado: (2020)

Facile synthesis of telechelic poly(phenylene sulfide)s by means of electron-deficient aromatic sulfonium electrophiles
por: Watanabe, Seigo, et al.
Publicado: (2023)

Direct Synthesis of α‐Aryl‐α‐Trifluoromethyl Alcohols via Nickel Catalyzed Cross‐Electrophile Coupling
por: Lombardi, Lorenzo, et al.
Publicado: (2022)

Regioselective Electrophilic Aromatic Bromination: Theoretical Analysis and Experimental Verification
por: Li, Hui-Jing, et al.
Publicado: (2014)

Decarboxylative Cross-Electrophile Coupling of N-Hydroxyphthalimide Esters with Aryl Iodides
por: Huihui, Kierra M. M., et al.
Publicado: (2016)

Oxidative Addition of Aryl Electrophiles into a Red-Light-Active Bismuthinidene
por: Mato, Mauro, et al.
Publicado: (2023)

Catalyst-Free Site Selective Hydroxyalkylation of 5-Phenylthiophen-2-amine with α-Trifluoromethyl Ketones through Electrophilic Aromatic Substitution
por: Duvauchelle, Valentin, et al.
Publicado: (2022)

Ni-catalyzed cross-electrophile coupling between vinyl/aryl and alkyl sulfonates: synthesis of cycloalkenes and modification of peptides
por: Duan, Jicheng, et al.
Publicado: (2019)

A methylation platform of unconventional inert aryl electrophiles: trimethylboroxine as a universal methylating reagent
por: Feng, Boya, et al.
Publicado: (2020)

N-Phenylanthranilic anhydride
por: Liu, Guan-Feng, et al.
Publicado: (2009)

An Efficient Synthesis of Arylated Pyridines from Conjugated Acetylenes and Substituted Benzylamines Catalyzed by Base
por: Guo, Mengping, et al.
Publicado: (2017)

Microbial-Derived Tryptophan Metabolites and Their Role in Neurological Disease: Anthranilic Acid and Anthranilic Acid Derivatives
por: Shaw, Claire, et al.
Publicado: (2023)

Enantioselective and Regiodivergent Copper-Catalyzed Electrophilic Arylation of Allylic Amides with Diaryliodonium Salts
por: Cahard, Elise, et al.
Publicado: (2015)

Nickel-catalysed cross-electrophile coupling of aryl bromides and primary alkyl bromides
por: Gao, Nanxing, et al.
Publicado: (2022)

C(sp(3))-Arylation by Conformationally Accelerated Intramolecular Nucleophilic Aromatic Substitution (S(N)Ar)
por: Wales, Steven M., et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_evtvquel4fqmat7okkbkgrngd7