Accessing Grignard Reluctant Aldehyde in 2-Oxoaldehyde by Organocuprates to Give [1,2] Addition and Oxidative Coupling Reactions

[Image: see text] Novel finding of aldehyde in 2-oxoaldehyde (2OA) is presented as it unprecedentedly disinclines to react with Grignard reagents but reacts with moderate organocuprate reagents in anaerobic condition to give [1,2] addition (α-hydroxyketones) reaction. In the presence of air, the rea...

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Detalles Bibliográficos
Autores principales: Battula, Satyanarayana, Desai, Aman A., Soni, Jigar Y., Mehta, Dhruv P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8851654/
https://www.ncbi.nlm.nih.gov/pubmed/35187323
http://dx.doi.org/10.1021/acsomega.1c06031

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8851654/
https://www.ncbi.nlm.nih.gov/pubmed/35187323
http://dx.doi.org/10.1021/acsomega.1c06031

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