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Cooperative Weak Dispersive Interactions Actuate Catalysis in a Shape-Selective Abiological Racemase

[Image: see text] A simple abiological host–guest system demonstrates racemase activity with catalytic rate enhancements of 10(4) without employing traditional functional groups. Cooperative weak interactions enhanced through shape-complementarity between the catalyst active site and the reaction tr...

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Detalles Bibliográficos
Autores principales: Wang, Yujia, Rickhaus, Michel, Blacque, Olivier, Baldridge, Kim K., Juríček, Michal, Siegel, Jay S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8855437/
https://www.ncbi.nlm.nih.gov/pubmed/35120406
http://dx.doi.org/10.1021/jacs.1c11032