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Cooperative Weak Dispersive Interactions Actuate Catalysis in a Shape-Selective Abiological Racemase
[Image: see text] A simple abiological host–guest system demonstrates racemase activity with catalytic rate enhancements of 10(4) without employing traditional functional groups. Cooperative weak interactions enhanced through shape-complementarity between the catalyst active site and the reaction tr...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8855437/ https://www.ncbi.nlm.nih.gov/pubmed/35120406 http://dx.doi.org/10.1021/jacs.1c11032 |