A catalyst-free, temperature controlled gelation system for in-mold fabrication of microgels

Anisometric microgels are prepared via thermal crosslinking using an in-mold polymerization technique. Star-shaped poly(ethylene oxide-stat-propylene oxide) polymers, end-modified with amine and epoxy groups, form hydrogels, of which the mechanical properties and gelation rate can be adjusted by the...

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Autores principales: Krüger, Andreas J. D., Köhler, Jens, Cichosz, Stefan, Rose, Jonas C., Gehlen, David B., Haraszti, Tamás, Möller, Martin, De Laporte, Laura
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8860190/
https://www.ncbi.nlm.nih.gov/pubmed/29876553
http://dx.doi.org/10.1039/c8cc02478b
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author Krüger, Andreas J. D.
Köhler, Jens
Cichosz, Stefan
Rose, Jonas C.
Gehlen, David B.
Haraszti, Tamás
Möller, Martin
De Laporte, Laura
author_facet Krüger, Andreas J. D.
Köhler, Jens
Cichosz, Stefan
Rose, Jonas C.
Gehlen, David B.
Haraszti, Tamás
Möller, Martin
De Laporte, Laura
author_sort Krüger, Andreas J. D.
collection PubMed
description Anisometric microgels are prepared via thermal crosslinking using an in-mold polymerization technique. Star-shaped poly(ethylene oxide-stat-propylene oxide) polymers, end-modified with amine and epoxy groups, form hydrogels, of which the mechanical properties and gelation rate can be adjusted by the temperature, duration of heating, and polymer concentration. Depending on the microgel stiffness, the rod-shaped microgels self-assemble into ordered or disordered structures.
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spelling pubmed-88601902022-03-17 A catalyst-free, temperature controlled gelation system for in-mold fabrication of microgels Krüger, Andreas J. D. Köhler, Jens Cichosz, Stefan Rose, Jonas C. Gehlen, David B. Haraszti, Tamás Möller, Martin De Laporte, Laura Chem Commun (Camb) Chemistry Anisometric microgels are prepared via thermal crosslinking using an in-mold polymerization technique. Star-shaped poly(ethylene oxide-stat-propylene oxide) polymers, end-modified with amine and epoxy groups, form hydrogels, of which the mechanical properties and gelation rate can be adjusted by the temperature, duration of heating, and polymer concentration. Depending on the microgel stiffness, the rod-shaped microgels self-assemble into ordered or disordered structures. The Royal Society of Chemistry 2018-06-01 /pmc/articles/PMC8860190/ /pubmed/29876553 http://dx.doi.org/10.1039/c8cc02478b Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Krüger, Andreas J. D.
Köhler, Jens
Cichosz, Stefan
Rose, Jonas C.
Gehlen, David B.
Haraszti, Tamás
Möller, Martin
De Laporte, Laura
A catalyst-free, temperature controlled gelation system for in-mold fabrication of microgels
title A catalyst-free, temperature controlled gelation system for in-mold fabrication of microgels
title_full A catalyst-free, temperature controlled gelation system for in-mold fabrication of microgels
title_fullStr A catalyst-free, temperature controlled gelation system for in-mold fabrication of microgels
title_full_unstemmed A catalyst-free, temperature controlled gelation system for in-mold fabrication of microgels
title_short A catalyst-free, temperature controlled gelation system for in-mold fabrication of microgels
title_sort catalyst-free, temperature controlled gelation system for in-mold fabrication of microgels
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8860190/
https://www.ncbi.nlm.nih.gov/pubmed/29876553
http://dx.doi.org/10.1039/c8cc02478b
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