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Unraveling the reactivity of a cationic iminoborane: avenues to unusual boron cations

A cationic terminal iminoborane [Mes*N[triple bond, length as m-dash]B ← IPr(2)Me(2)][AlBr(4)] (3(+)[AlBr(4)](−)) (Mes* = 2,4,6-tri-tert-butylphenyl and IPr(2)Me(2) = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) has been synthesized and characterized. The employment of an aryl group and N-heteroc...

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Detalles Bibliográficos
Autores principales: Guo, Rui, Zhang, Xin, Li, Tong, Li, Qianli, Ruiz, David A., Liu, Liu Leo, Tung, Chen-Ho, Kong, Lingbing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8864711/
https://www.ncbi.nlm.nih.gov/pubmed/35310477
http://dx.doi.org/10.1039/d2sc00002d