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Ligand and solvent effects on CO(2) insertion into group 10 metal alkyl bonds

The insertion of carbon dioxide into metal element σ-bonds is an important elementary step in many catalytic reactions for carbon dioxide valorization. Here, the insertion of carbon dioxide into a family of group 10 alkyl complexes of the type ((R)PBP)M(CH(3)) ((R)PBP = B(NCH(2)PR(2))(2)C(6)H(4)(−);...

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Detalles Bibliográficos
Autores principales:	Deziel, Anthony P., Espinosa, Matthew R., Pavlovic, Ljiljana, Charboneau, David J., Hazari, Nilay, Hopmann, Kathrin H., Mercado, Brandon Q.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8867079/ https://www.ncbi.nlm.nih.gov/pubmed/35342547 http://dx.doi.org/10.1039/d1sc06346d

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