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Temperature-Based Selective Detection of Hydrogen Sulfide and Ethanol with MoS(2)/WO(3) Composite

[Image: see text] A sensitive and temperature-based selective sensor toward hydrogen sulfide and ethanol using MoS(2)/WO(3) composite as a sensing surface was developed in this work. The MoS(2)/WO(3) nanocomposite was successfully obtained using a facile two-step method. Structural analysis revealed...

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Autores principales: Singh, Sukhwinder, Sharma, Sandeep
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8867485/
https://www.ncbi.nlm.nih.gov/pubmed/35224369
http://dx.doi.org/10.1021/acsomega.1c06471
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author Singh, Sukhwinder
Sharma, Sandeep
author_facet Singh, Sukhwinder
Sharma, Sandeep
author_sort Singh, Sukhwinder
collection PubMed
description [Image: see text] A sensitive and temperature-based selective sensor toward hydrogen sulfide and ethanol using MoS(2)/WO(3) composite as a sensing surface was developed in this work. The MoS(2)/WO(3) nanocomposite was successfully obtained using a facile two-step method. Structural analysis revealed the successful formation of the composite. Further, the n-type semiconducting nature as revealed in the initial gas-sensing measurements was also confirmed via Mott–Schottky plots. The composite-based sensor showed preferential detection of ethanol (260 °C) and hydrogen sulfide (320 °C) by simply modulating the temperature of the sensor device. The device also displayed repeatability and long-term stability at respective operating temperatures. Improved sensitivity and selectivity are ascribed to synergistic effects arising from the formation of n–n type heterostructures. The present work indicates the potential use of composite-based heterojunctions to tune the sensing parameters and provide new possibilities to enhance the applications of MoS(2) and metal-oxide semiconductor-based composites.
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spelling pubmed-88674852022-02-25 Temperature-Based Selective Detection of Hydrogen Sulfide and Ethanol with MoS(2)/WO(3) Composite Singh, Sukhwinder Sharma, Sandeep ACS Omega [Image: see text] A sensitive and temperature-based selective sensor toward hydrogen sulfide and ethanol using MoS(2)/WO(3) composite as a sensing surface was developed in this work. The MoS(2)/WO(3) nanocomposite was successfully obtained using a facile two-step method. Structural analysis revealed the successful formation of the composite. Further, the n-type semiconducting nature as revealed in the initial gas-sensing measurements was also confirmed via Mott–Schottky plots. The composite-based sensor showed preferential detection of ethanol (260 °C) and hydrogen sulfide (320 °C) by simply modulating the temperature of the sensor device. The device also displayed repeatability and long-term stability at respective operating temperatures. Improved sensitivity and selectivity are ascribed to synergistic effects arising from the formation of n–n type heterostructures. The present work indicates the potential use of composite-based heterojunctions to tune the sensing parameters and provide new possibilities to enhance the applications of MoS(2) and metal-oxide semiconductor-based composites. American Chemical Society 2022-02-07 /pmc/articles/PMC8867485/ /pubmed/35224369 http://dx.doi.org/10.1021/acsomega.1c06471 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Singh, Sukhwinder
Sharma, Sandeep
Temperature-Based Selective Detection of Hydrogen Sulfide and Ethanol with MoS(2)/WO(3) Composite
title Temperature-Based Selective Detection of Hydrogen Sulfide and Ethanol with MoS(2)/WO(3) Composite
title_full Temperature-Based Selective Detection of Hydrogen Sulfide and Ethanol with MoS(2)/WO(3) Composite
title_fullStr Temperature-Based Selective Detection of Hydrogen Sulfide and Ethanol with MoS(2)/WO(3) Composite
title_full_unstemmed Temperature-Based Selective Detection of Hydrogen Sulfide and Ethanol with MoS(2)/WO(3) Composite
title_short Temperature-Based Selective Detection of Hydrogen Sulfide and Ethanol with MoS(2)/WO(3) Composite
title_sort temperature-based selective detection of hydrogen sulfide and ethanol with mos(2)/wo(3) composite
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8867485/
https://www.ncbi.nlm.nih.gov/pubmed/35224369
http://dx.doi.org/10.1021/acsomega.1c06471
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