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The surprising effects of sulfur: achieving long excited-state lifetimes in heteroleptic copper(i) emitters

A series of heteroleptic [Cu(N^N)(P^P)][PF(6)] complexes is reported in which N^N is a di(methylsulfanyl)-1,10-phenanthroline (2,9-, 3,8- or 4,7-(MeS)(2)phen) or di(methoxy)-1,10-phenanthroline (2,9-, 3,8- or 4,7-(MeO)(2)phen) and P^P is bis(2-(diphenylphosphano)phenyl)ether (POP) or 4,5-bis(dipheny...

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Detalles Bibliográficos
Autores principales:	Nohara, Isaak, Wegeberg, Christina, Devereux, Mike, Prescimone, Alessandro, Housecroft, Catherine E., Constable, Edwin C.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8870442/ https://www.ncbi.nlm.nih.gov/pubmed/35340713 http://dx.doi.org/10.1039/d1tc05591g

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