Cargando…

Accumulation of Particles and Formation of a Dissipative Structure in a Nonequilibrium Bath

The standard textbooks contain good explanations of how and why equilibrium thermodynamics emerges in a reservoir with particles that are subjected to Gaussian noise. However, in systems that convert or transport energy, the noise is often not Gaussian. Instead, displacements exhibit an [Formula: se...

Descripción completa

Detalles Bibliográficos
Autores principales: Yuvan, Steven, Bier, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8870893/
https://www.ncbi.nlm.nih.gov/pubmed/35205484
http://dx.doi.org/10.3390/e24020189
_version_ 1784656866105622528
author Yuvan, Steven
Bier, Martin
author_facet Yuvan, Steven
Bier, Martin
author_sort Yuvan, Steven
collection PubMed
description The standard textbooks contain good explanations of how and why equilibrium thermodynamics emerges in a reservoir with particles that are subjected to Gaussian noise. However, in systems that convert or transport energy, the noise is often not Gaussian. Instead, displacements exhibit an [Formula: see text]-stable distribution. Such noise is commonly called Lévy noise. With such noise, we see a thermodynamics that deviates from what traditional equilibrium theory stipulates. In addition, with particles that can propel themselves, so-called active particles, we find that the rules of equilibrium thermodynamics no longer apply. No general nonequilibrium thermodynamic theory is available and understanding is often ad hoc. We study a system with overdamped particles that are subjected to Lévy noise. We pick a system with a geometry that leads to concise formulae to describe the accumulation of particles in a cavity. The nonhomogeneous distribution of particles can be seen as a dissipative structure, i.e., a lower-entropy steady state that allows for throughput of energy and concurrent production of entropy. After the mechanism that maintains nonequilibrium is switched off, the relaxation back to homogeneity represents an increase in entropy and a decrease of free energy. For our setup we can analytically connect the nonequilibrium noise and active particle behavior to entropy decrease and energy buildup with simple and intuitive formulae.
format Online
Article
Text
id pubmed-8870893
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher MDPI
record_format MEDLINE/PubMed
spelling pubmed-88708932022-02-25 Accumulation of Particles and Formation of a Dissipative Structure in a Nonequilibrium Bath Yuvan, Steven Bier, Martin Entropy (Basel) Article The standard textbooks contain good explanations of how and why equilibrium thermodynamics emerges in a reservoir with particles that are subjected to Gaussian noise. However, in systems that convert or transport energy, the noise is often not Gaussian. Instead, displacements exhibit an [Formula: see text]-stable distribution. Such noise is commonly called Lévy noise. With such noise, we see a thermodynamics that deviates from what traditional equilibrium theory stipulates. In addition, with particles that can propel themselves, so-called active particles, we find that the rules of equilibrium thermodynamics no longer apply. No general nonequilibrium thermodynamic theory is available and understanding is often ad hoc. We study a system with overdamped particles that are subjected to Lévy noise. We pick a system with a geometry that leads to concise formulae to describe the accumulation of particles in a cavity. The nonhomogeneous distribution of particles can be seen as a dissipative structure, i.e., a lower-entropy steady state that allows for throughput of energy and concurrent production of entropy. After the mechanism that maintains nonequilibrium is switched off, the relaxation back to homogeneity represents an increase in entropy and a decrease of free energy. For our setup we can analytically connect the nonequilibrium noise and active particle behavior to entropy decrease and energy buildup with simple and intuitive formulae. MDPI 2022-01-27 /pmc/articles/PMC8870893/ /pubmed/35205484 http://dx.doi.org/10.3390/e24020189 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Yuvan, Steven
Bier, Martin
Accumulation of Particles and Formation of a Dissipative Structure in a Nonequilibrium Bath
title Accumulation of Particles and Formation of a Dissipative Structure in a Nonequilibrium Bath
title_full Accumulation of Particles and Formation of a Dissipative Structure in a Nonequilibrium Bath
title_fullStr Accumulation of Particles and Formation of a Dissipative Structure in a Nonequilibrium Bath
title_full_unstemmed Accumulation of Particles and Formation of a Dissipative Structure in a Nonequilibrium Bath
title_short Accumulation of Particles and Formation of a Dissipative Structure in a Nonequilibrium Bath
title_sort accumulation of particles and formation of a dissipative structure in a nonequilibrium bath
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8870893/
https://www.ncbi.nlm.nih.gov/pubmed/35205484
http://dx.doi.org/10.3390/e24020189
work_keys_str_mv AT yuvansteven accumulationofparticlesandformationofadissipativestructureinanonequilibriumbath
AT biermartin accumulationofparticlesandformationofadissipativestructureinanonequilibriumbath