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Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization

Polyolefins are used in everyday life, including in the production of many types of plastic. In addition, polyolefins account for over 50% of the polymers produced in the world. After conducting the oligomerization reactions of 2-propen-1-ol, 2-chloro-2-propen-1-ol, and norborene, polyolefins are ob...

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Autores principales: Drzeżdżon, Joanna, Pawlak, Marta, Gawdzik, Barbara, Wypych, Aleksandra, Kramkowski, Karol, Kowalczyk, Paweł, Jacewicz, Dagmara
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8875215/
https://www.ncbi.nlm.nih.gov/pubmed/35207920
http://dx.doi.org/10.3390/ma15041379
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author Drzeżdżon, Joanna
Pawlak, Marta
Gawdzik, Barbara
Wypych, Aleksandra
Kramkowski, Karol
Kowalczyk, Paweł
Jacewicz, Dagmara
author_facet Drzeżdżon, Joanna
Pawlak, Marta
Gawdzik, Barbara
Wypych, Aleksandra
Kramkowski, Karol
Kowalczyk, Paweł
Jacewicz, Dagmara
author_sort Drzeżdżon, Joanna
collection PubMed
description Polyolefins are used in everyday life, including in the production of many types of plastic. In addition, polyolefins account for over 50% of the polymers produced in the world. After conducting the oligomerization reactions of 2-propen-1-ol, 2-chloro-2-propen-1-ol, and norborene, polyolefins are obtained. In this report, two complexes of oxovanadium(IV) and dioxovanadium(V) with dipicolinate, 2-phenylyridine, and 4,4′-dimethoxy-2,2′-bipyridyl as precatalysts for 2-propen-1-ol, 2-chloro-2-propen-1-ol, and norborene oligomerizations are prepared. We present for the first time the new dipicolinate complex compound of oxovanadium(IV) with 4,4′-dimetoxy-2,2′-bipyridyl. Both complexes were tested for catalytic activity in the oligomerization reactions of 2-propen-1-ol, 2-chloro-2-propen-1-ol, and norbornene. Both synthesized complexes showed high catalytic activity in these oligomerization reactions, except for the oligomerization of norbornene.
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spelling pubmed-88752152022-02-26 Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization Drzeżdżon, Joanna Pawlak, Marta Gawdzik, Barbara Wypych, Aleksandra Kramkowski, Karol Kowalczyk, Paweł Jacewicz, Dagmara Materials (Basel) Article Polyolefins are used in everyday life, including in the production of many types of plastic. In addition, polyolefins account for over 50% of the polymers produced in the world. After conducting the oligomerization reactions of 2-propen-1-ol, 2-chloro-2-propen-1-ol, and norborene, polyolefins are obtained. In this report, two complexes of oxovanadium(IV) and dioxovanadium(V) with dipicolinate, 2-phenylyridine, and 4,4′-dimethoxy-2,2′-bipyridyl as precatalysts for 2-propen-1-ol, 2-chloro-2-propen-1-ol, and norborene oligomerizations are prepared. We present for the first time the new dipicolinate complex compound of oxovanadium(IV) with 4,4′-dimetoxy-2,2′-bipyridyl. Both complexes were tested for catalytic activity in the oligomerization reactions of 2-propen-1-ol, 2-chloro-2-propen-1-ol, and norbornene. Both synthesized complexes showed high catalytic activity in these oligomerization reactions, except for the oligomerization of norbornene. MDPI 2022-02-13 /pmc/articles/PMC8875215/ /pubmed/35207920 http://dx.doi.org/10.3390/ma15041379 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Drzeżdżon, Joanna
Pawlak, Marta
Gawdzik, Barbara
Wypych, Aleksandra
Kramkowski, Karol
Kowalczyk, Paweł
Jacewicz, Dagmara
Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization
title Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization
title_full Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization
title_fullStr Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization
title_full_unstemmed Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization
title_short Dipicolinate Complexes of Oxovanadium(IV) and Dioxovanadium(V) with 2-Phenylpyridine and 4,4′-Dimethoxy-2,2′-bipyridyl as New Precatalysts for Olefin Oligomerization
title_sort dipicolinate complexes of oxovanadium(iv) and dioxovanadium(v) with 2-phenylpyridine and 4,4′-dimethoxy-2,2′-bipyridyl as new precatalysts for olefin oligomerization
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8875215/
https://www.ncbi.nlm.nih.gov/pubmed/35207920
http://dx.doi.org/10.3390/ma15041379
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