Influence of Pentaerythritol Tetraacrylate Crosslinker on Polycarboxylate Superplasticizer Performance in Cementitious System

In this work, a crosslinked polycarboxylate superplasticizer (crosslinked-PC) was synthesized via the free radical polymerization reaction. Pentaerythritol tetraacrylate (PETA) was used as the crosslinked agent. A comparative comb-like polycarboxylate superplasticizer (comb-like-PC) was prepared under the same reaction conditions. The dispersion retention capacity, dispersion capability, hydration characteristics of the cement paste and setting time were investigated in detail. At the dosage of 0.6% bwoc, the fluidity of the cement/crosslinked-PC paste was about 340 mm, which was 40~50 mm larger than the cement/comb-like-PC paste. The dispersion retention capacity of the cement/crosslinked-PC paste was observed to be much superior due to higher adsorbed amounts on the cement particles. Moreover, the cement/crosslinked-PC paste exhibited the initial and final setting durations of 196 and 356 min, respectively, which indicated an enhancement of 18 and 68 min compared to the cement/comb-like paste. The crosslinked copolymers exhibit a stronger retardation effect than the comb-like copolymers due to their enhanced adsorbed amounts and stronger steric hindrance effect. This is further illustrated by the characterization of the hydration process and hydration products. It can be concluded that it is feasible to improve the dispersive capacity and the dispersion retention capacity of PC by changing the molecule structure from comb-like to slightly crosslinked.