Characteristics of Inorganic–Organic Hybrid Membranes Containing Carbon Nanotubes with Increased Iron-Encapsulated Content for CO(2) Separation

Novel inorganic–organic hybrid membranes Fe@MWCNT/PPO or Fe@MWCNT-OH/SPPO (with a new type of CNTs characterized by increased iron content 5.80 wt%) were synthesized for CO(2) separation. The introduction of nanofillers into the polymer matrix has significantly improved the hybrid membrane’s gas transport (D, P, S, and α(CO(2)/N(2))), magnetic, thermal, and mechanical parameters. It was found that magnetic casting has improved the alignment and dispersion of Fe@MWCNTs. At the same time, CNTs and polymer chemical modification enhanced interphase compatibility and the membrane’s CO(2) separation efficiency. The thermo-oxidative stability and mechanical and magnetic parameters of composites were improved by increasing new CNTs loading. Cherazi’s model turned out to be suitable for describing the CO(2) transport through analyzed hybrid membranes.