Zn(II) and Co(II) 3D Coordination Polymers Based on 2-Iodoterephtalic Acid and 1,2-bis(4-pyridyl)ethane: Structures and Sorption Properties

Metal-organic frameworks [M(2)(2-I-bdc)(2)bpe] (M = Zn(II) (1), Co(II) (2), 2-I-bdc = 2-iodoterephtalic acid, and bpe = 1,2-bis(4-pyridyl)ethane) were prepared and characterized by X-ray diffractometry. Both compounds retain their 3D structure after the removal of guest DMF molecules. Selectivity of...

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Detalles Bibliográficos
Autores principales: Zaguzin, Alexander S., Sukhikh, Taisiya S., Sakhapov, Ilyas F., Fedin, Vladimir P., Sokolov, Maxim N., Adonin, Sergey A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8876937/
https://www.ncbi.nlm.nih.gov/pubmed/35209092
http://dx.doi.org/10.3390/molecules27041305
Descripción
Sumario:Metal-organic frameworks [M(2)(2-I-bdc)(2)bpe] (M = Zn(II) (1), Co(II) (2), 2-I-bdc = 2-iodoterephtalic acid, and bpe = 1,2-bis(4-pyridyl)ethane) were prepared and characterized by X-ray diffractometry. Both compounds retain their 3D structure after the removal of guest DMF molecules. Selectivity of sorption of different organic substrates from the gas phase was investigated for both complexes.

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