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Synthesis and Characterization of an α-Fe(2)O(3)-Decorated g-C(3)N(4) Heterostructure for the Photocatalytic Removal of MO
This study describes the preparation of graphitic carbon nitride (g-C(3)N(4)), hematite (α-Fe(2)O(3)), and their g-C(3)N(4)/α-Fe(2)O(3) heterostructure for the photocatalytic removal of methyl orange (MO) under visible light illumination. The facile hydrothermal approach was utilized for the prepara...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8877162/ https://www.ncbi.nlm.nih.gov/pubmed/35209230 http://dx.doi.org/10.3390/molecules27041442 |
Sumario: | This study describes the preparation of graphitic carbon nitride (g-C(3)N(4)), hematite (α-Fe(2)O(3)), and their g-C(3)N(4)/α-Fe(2)O(3) heterostructure for the photocatalytic removal of methyl orange (MO) under visible light illumination. The facile hydrothermal approach was utilized for the preparation of the nanomaterials. Powder X-ray diffraction (XRD), Scanning electron microscopy (SEM), Energy dispersive X-ray (EDX), and Brunauer–Emmett–Teller (BET) were carried out to study the physiochemical and optoelectronic properties of all the synthesized photocatalysts. Based on the X-ray photoelectron spectroscopy (XPS) and UV-visible diffuse reflectance (DRS) results, an energy level diagram vs. SHE was established. The acquired results indicated that the nanocomposite exhibited a type-II heterojunction and degraded the MO dye by 97%. The degradation ability of the nanocomposite was higher than that of pristine g-C(3)N(4) (41%) and α-Fe(2)O(3) (30%) photocatalysts under 300 min of light irradiation. The formation of a type-II heterostructure with desirable band alignment and band edge positions for efficient interfacial charge carrier separation along with a larger specific surface area was collectively responsible for the higher photocatalytic efficiency of the g-C(3)N(4)/α-Fe(2)O(3) nanocomposite. The mechanism of the nanocomposite was also studied through results obtained from UV-vis and XPS analyses. A reactive species trapping experiment confirmed the involvement of the superoxide radical anion (O(2)(•−)) as the key reactive oxygen species for MO removal. The degradation kinetics were also monitored, and the reaction was observed to be pseudo-first order. Moreover, the sustainability of the photocatalyst was also investigated. |
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