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Synthesis and Characterization of an α-Fe(2)O(3)-Decorated g-C(3)N(4) Heterostructure for the Photocatalytic Removal of MO
This study describes the preparation of graphitic carbon nitride (g-C(3)N(4)), hematite (α-Fe(2)O(3)), and their g-C(3)N(4)/α-Fe(2)O(3) heterostructure for the photocatalytic removal of methyl orange (MO) under visible light illumination. The facile hydrothermal approach was utilized for the prepara...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8877162/ https://www.ncbi.nlm.nih.gov/pubmed/35209230 http://dx.doi.org/10.3390/molecules27041442 |
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author | Khurram, Rooha Nisa, Zaib Un Javed, Aroosa Wang, Zhan Hussien, Mostafa A. |
author_facet | Khurram, Rooha Nisa, Zaib Un Javed, Aroosa Wang, Zhan Hussien, Mostafa A. |
author_sort | Khurram, Rooha |
collection | PubMed |
description | This study describes the preparation of graphitic carbon nitride (g-C(3)N(4)), hematite (α-Fe(2)O(3)), and their g-C(3)N(4)/α-Fe(2)O(3) heterostructure for the photocatalytic removal of methyl orange (MO) under visible light illumination. The facile hydrothermal approach was utilized for the preparation of the nanomaterials. Powder X-ray diffraction (XRD), Scanning electron microscopy (SEM), Energy dispersive X-ray (EDX), and Brunauer–Emmett–Teller (BET) were carried out to study the physiochemical and optoelectronic properties of all the synthesized photocatalysts. Based on the X-ray photoelectron spectroscopy (XPS) and UV-visible diffuse reflectance (DRS) results, an energy level diagram vs. SHE was established. The acquired results indicated that the nanocomposite exhibited a type-II heterojunction and degraded the MO dye by 97%. The degradation ability of the nanocomposite was higher than that of pristine g-C(3)N(4) (41%) and α-Fe(2)O(3) (30%) photocatalysts under 300 min of light irradiation. The formation of a type-II heterostructure with desirable band alignment and band edge positions for efficient interfacial charge carrier separation along with a larger specific surface area was collectively responsible for the higher photocatalytic efficiency of the g-C(3)N(4)/α-Fe(2)O(3) nanocomposite. The mechanism of the nanocomposite was also studied through results obtained from UV-vis and XPS analyses. A reactive species trapping experiment confirmed the involvement of the superoxide radical anion (O(2)(•−)) as the key reactive oxygen species for MO removal. The degradation kinetics were also monitored, and the reaction was observed to be pseudo-first order. Moreover, the sustainability of the photocatalyst was also investigated. |
format | Online Article Text |
id | pubmed-8877162 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-88771622022-02-26 Synthesis and Characterization of an α-Fe(2)O(3)-Decorated g-C(3)N(4) Heterostructure for the Photocatalytic Removal of MO Khurram, Rooha Nisa, Zaib Un Javed, Aroosa Wang, Zhan Hussien, Mostafa A. Molecules Article This study describes the preparation of graphitic carbon nitride (g-C(3)N(4)), hematite (α-Fe(2)O(3)), and their g-C(3)N(4)/α-Fe(2)O(3) heterostructure for the photocatalytic removal of methyl orange (MO) under visible light illumination. The facile hydrothermal approach was utilized for the preparation of the nanomaterials. Powder X-ray diffraction (XRD), Scanning electron microscopy (SEM), Energy dispersive X-ray (EDX), and Brunauer–Emmett–Teller (BET) were carried out to study the physiochemical and optoelectronic properties of all the synthesized photocatalysts. Based on the X-ray photoelectron spectroscopy (XPS) and UV-visible diffuse reflectance (DRS) results, an energy level diagram vs. SHE was established. The acquired results indicated that the nanocomposite exhibited a type-II heterojunction and degraded the MO dye by 97%. The degradation ability of the nanocomposite was higher than that of pristine g-C(3)N(4) (41%) and α-Fe(2)O(3) (30%) photocatalysts under 300 min of light irradiation. The formation of a type-II heterostructure with desirable band alignment and band edge positions for efficient interfacial charge carrier separation along with a larger specific surface area was collectively responsible for the higher photocatalytic efficiency of the g-C(3)N(4)/α-Fe(2)O(3) nanocomposite. The mechanism of the nanocomposite was also studied through results obtained from UV-vis and XPS analyses. A reactive species trapping experiment confirmed the involvement of the superoxide radical anion (O(2)(•−)) as the key reactive oxygen species for MO removal. The degradation kinetics were also monitored, and the reaction was observed to be pseudo-first order. Moreover, the sustainability of the photocatalyst was also investigated. MDPI 2022-02-21 /pmc/articles/PMC8877162/ /pubmed/35209230 http://dx.doi.org/10.3390/molecules27041442 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Khurram, Rooha Nisa, Zaib Un Javed, Aroosa Wang, Zhan Hussien, Mostafa A. Synthesis and Characterization of an α-Fe(2)O(3)-Decorated g-C(3)N(4) Heterostructure for the Photocatalytic Removal of MO |
title | Synthesis and Characterization of an α-Fe(2)O(3)-Decorated g-C(3)N(4) Heterostructure for the Photocatalytic Removal of MO |
title_full | Synthesis and Characterization of an α-Fe(2)O(3)-Decorated g-C(3)N(4) Heterostructure for the Photocatalytic Removal of MO |
title_fullStr | Synthesis and Characterization of an α-Fe(2)O(3)-Decorated g-C(3)N(4) Heterostructure for the Photocatalytic Removal of MO |
title_full_unstemmed | Synthesis and Characterization of an α-Fe(2)O(3)-Decorated g-C(3)N(4) Heterostructure for the Photocatalytic Removal of MO |
title_short | Synthesis and Characterization of an α-Fe(2)O(3)-Decorated g-C(3)N(4) Heterostructure for the Photocatalytic Removal of MO |
title_sort | synthesis and characterization of an α-fe(2)o(3)-decorated g-c(3)n(4) heterostructure for the photocatalytic removal of mo |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8877162/ https://www.ncbi.nlm.nih.gov/pubmed/35209230 http://dx.doi.org/10.3390/molecules27041442 |
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