Cargando…

Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ)—A Novel Bifunctional Electrocatalyst for Oxygen Reduction/Evolution Reactions

The development of non-precious metal catalysts with excellent bifunctional activities is significant for air–metal batteries. ABO(3)-type perovskite oxides can improve their catalytic activity and electronic conductivity by doping transition metal elements at B sites. Here, we develop a novel Sm(0....

Descripción completa

Detalles Bibliográficos
Autores principales: Liu, Xingmei, Wang, Yuwei, Fan, Liquan, Zhang, Weichao, Cao, Weiyan, Han, Xianxin, Liu, Xijun, Jia, Hongge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8877539/
https://www.ncbi.nlm.nih.gov/pubmed/35209051
http://dx.doi.org/10.3390/molecules27041263
Descripción
Sumario:The development of non-precious metal catalysts with excellent bifunctional activities is significant for air–metal batteries. ABO(3)-type perovskite oxides can improve their catalytic activity and electronic conductivity by doping transition metal elements at B sites. Here, we develop a novel Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ) (SSCN) nanofiber-structured electrocatalyst. In 0.1 M KOH electrolyte solution, Sm(0.5)Sr(0.5)Co(0.8)Ni(0.2)O(3−δ) (SSCN82) with the optimal Co: Ni molar ratio exhibits good electrocatalytic activity for OER/ORR, affording a low onset potential of 1.39 V, a slight Tafel slope of 123.8 mV dec(−1), and a current density of 6.01 mA cm(−2) at 1.8 V, and the ORR reaction process was four-electron reaction pathway. Combining the morphological characteristic of SSCN nanofibers with the synergistic effect of cobalt and nickel with a suitable molar ratio is beneficial to improving the catalytic activity of SSCN perovskite oxides. SSCN82 exhibits good bi-functional catalytic performance and electrochemical double-layer capacitance.