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Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ)—A Novel Bifunctional Electrocatalyst for Oxygen Reduction/Evolution Reactions

The development of non-precious metal catalysts with excellent bifunctional activities is significant for air–metal batteries. ABO(3)-type perovskite oxides can improve their catalytic activity and electronic conductivity by doping transition metal elements at B sites. Here, we develop a novel Sm(0....

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Detalles Bibliográficos
Autores principales: Liu, Xingmei, Wang, Yuwei, Fan, Liquan, Zhang, Weichao, Cao, Weiyan, Han, Xianxin, Liu, Xijun, Jia, Hongge
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8877539/
https://www.ncbi.nlm.nih.gov/pubmed/35209051
http://dx.doi.org/10.3390/molecules27041263
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author Liu, Xingmei
Wang, Yuwei
Fan, Liquan
Zhang, Weichao
Cao, Weiyan
Han, Xianxin
Liu, Xijun
Jia, Hongge
author_facet Liu, Xingmei
Wang, Yuwei
Fan, Liquan
Zhang, Weichao
Cao, Weiyan
Han, Xianxin
Liu, Xijun
Jia, Hongge
author_sort Liu, Xingmei
collection PubMed
description The development of non-precious metal catalysts with excellent bifunctional activities is significant for air–metal batteries. ABO(3)-type perovskite oxides can improve their catalytic activity and electronic conductivity by doping transition metal elements at B sites. Here, we develop a novel Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ) (SSCN) nanofiber-structured electrocatalyst. In 0.1 M KOH electrolyte solution, Sm(0.5)Sr(0.5)Co(0.8)Ni(0.2)O(3−δ) (SSCN82) with the optimal Co: Ni molar ratio exhibits good electrocatalytic activity for OER/ORR, affording a low onset potential of 1.39 V, a slight Tafel slope of 123.8 mV dec(−1), and a current density of 6.01 mA cm(−2) at 1.8 V, and the ORR reaction process was four-electron reaction pathway. Combining the morphological characteristic of SSCN nanofibers with the synergistic effect of cobalt and nickel with a suitable molar ratio is beneficial to improving the catalytic activity of SSCN perovskite oxides. SSCN82 exhibits good bi-functional catalytic performance and electrochemical double-layer capacitance.
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spelling pubmed-88775392022-02-26 Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ)—A Novel Bifunctional Electrocatalyst for Oxygen Reduction/Evolution Reactions Liu, Xingmei Wang, Yuwei Fan, Liquan Zhang, Weichao Cao, Weiyan Han, Xianxin Liu, Xijun Jia, Hongge Molecules Article The development of non-precious metal catalysts with excellent bifunctional activities is significant for air–metal batteries. ABO(3)-type perovskite oxides can improve their catalytic activity and electronic conductivity by doping transition metal elements at B sites. Here, we develop a novel Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ) (SSCN) nanofiber-structured electrocatalyst. In 0.1 M KOH electrolyte solution, Sm(0.5)Sr(0.5)Co(0.8)Ni(0.2)O(3−δ) (SSCN82) with the optimal Co: Ni molar ratio exhibits good electrocatalytic activity for OER/ORR, affording a low onset potential of 1.39 V, a slight Tafel slope of 123.8 mV dec(−1), and a current density of 6.01 mA cm(−2) at 1.8 V, and the ORR reaction process was four-electron reaction pathway. Combining the morphological characteristic of SSCN nanofibers with the synergistic effect of cobalt and nickel with a suitable molar ratio is beneficial to improving the catalytic activity of SSCN perovskite oxides. SSCN82 exhibits good bi-functional catalytic performance and electrochemical double-layer capacitance. MDPI 2022-02-14 /pmc/articles/PMC8877539/ /pubmed/35209051 http://dx.doi.org/10.3390/molecules27041263 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Liu, Xingmei
Wang, Yuwei
Fan, Liquan
Zhang, Weichao
Cao, Weiyan
Han, Xianxin
Liu, Xijun
Jia, Hongge
Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ)—A Novel Bifunctional Electrocatalyst for Oxygen Reduction/Evolution Reactions
title Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ)—A Novel Bifunctional Electrocatalyst for Oxygen Reduction/Evolution Reactions
title_full Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ)—A Novel Bifunctional Electrocatalyst for Oxygen Reduction/Evolution Reactions
title_fullStr Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ)—A Novel Bifunctional Electrocatalyst for Oxygen Reduction/Evolution Reactions
title_full_unstemmed Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ)—A Novel Bifunctional Electrocatalyst for Oxygen Reduction/Evolution Reactions
title_short Sm(0.5)Sr(0.5)Co(1−x)Ni(x)O(3−δ)—A Novel Bifunctional Electrocatalyst for Oxygen Reduction/Evolution Reactions
title_sort sm(0.5)sr(0.5)co(1−x)ni(x)o(3−δ)—a novel bifunctional electrocatalyst for oxygen reduction/evolution reactions
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8877539/
https://www.ncbi.nlm.nih.gov/pubmed/35209051
http://dx.doi.org/10.3390/molecules27041263
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