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A Convenient and Simple Ionic Polymer-Metal Composite (IPMC) Actuator Based on a Platinum-Coated Sulfonated Poly(ether ether ketone)–Polyaniline Composite Membrane

Herein, we present new approaches for developing sulfonated polyether ether ketone (SPEEK) and polyaniline-based (PANI) actuator formed by film-casting and chemical reduction of Pt electrodes. We have thoroughly studied the synthesis of SPEEK and characterized it by different analytical techniques....

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Autores principales: Luqman, Mohammad, Shaikh, Hamid M., Anis, Arfat, Al-Zahrani, Saeed M., Alam, Mohammad Asif
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8879763/
https://www.ncbi.nlm.nih.gov/pubmed/35215581
http://dx.doi.org/10.3390/polym14040668
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author Luqman, Mohammad
Shaikh, Hamid M.
Anis, Arfat
Al-Zahrani, Saeed M.
Alam, Mohammad Asif
author_facet Luqman, Mohammad
Shaikh, Hamid M.
Anis, Arfat
Al-Zahrani, Saeed M.
Alam, Mohammad Asif
author_sort Luqman, Mohammad
collection PubMed
description Herein, we present new approaches for developing sulfonated polyether ether ketone (SPEEK) and polyaniline-based (PANI) actuator formed by film-casting and chemical reduction of Pt electrodes. We have thoroughly studied the synthesis of SPEEK and characterized it by different analytical techniques. The ion-exchange capacity (IEC) and proton conductivity of SPEEK-PANI polymer membrane were calculated to be 1.98 mmol g(−1) and 1.97 × 10(−3) S cm(−1), respectively. To develop an IPMC actuator, SPEEK was combined with PANI through in-situ polymerization method. SEM and XRD were used to check the morphology of the given SPEEK-PANI-Pt membrane. In addition, FT-IR and EDX techniques confirmed the molecular structure and chemical conformation of SPEEK-PANI polymer membrane. Pt electrode layers homogeneously dispersed on the IPMC membrane surface, which was demonstrated by smooth SEM micrographs. The actuation functioning, including the high bending deflection, proton conductivity, current density and IEC of IPMC actuator based on SPEEK-PANI-Pt, was obtained owing to its strong electrochemical and electromechanical characteristics. Synergistic combinations of SPEEK and PANI produced membrane that are flexible, mechanically strong and robust. The developed materials have immense capability as actuators for various applications including in biomimetics and robotics.
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spelling pubmed-88797632022-02-26 A Convenient and Simple Ionic Polymer-Metal Composite (IPMC) Actuator Based on a Platinum-Coated Sulfonated Poly(ether ether ketone)–Polyaniline Composite Membrane Luqman, Mohammad Shaikh, Hamid M. Anis, Arfat Al-Zahrani, Saeed M. Alam, Mohammad Asif Polymers (Basel) Article Herein, we present new approaches for developing sulfonated polyether ether ketone (SPEEK) and polyaniline-based (PANI) actuator formed by film-casting and chemical reduction of Pt electrodes. We have thoroughly studied the synthesis of SPEEK and characterized it by different analytical techniques. The ion-exchange capacity (IEC) and proton conductivity of SPEEK-PANI polymer membrane were calculated to be 1.98 mmol g(−1) and 1.97 × 10(−3) S cm(−1), respectively. To develop an IPMC actuator, SPEEK was combined with PANI through in-situ polymerization method. SEM and XRD were used to check the morphology of the given SPEEK-PANI-Pt membrane. In addition, FT-IR and EDX techniques confirmed the molecular structure and chemical conformation of SPEEK-PANI polymer membrane. Pt electrode layers homogeneously dispersed on the IPMC membrane surface, which was demonstrated by smooth SEM micrographs. The actuation functioning, including the high bending deflection, proton conductivity, current density and IEC of IPMC actuator based on SPEEK-PANI-Pt, was obtained owing to its strong electrochemical and electromechanical characteristics. Synergistic combinations of SPEEK and PANI produced membrane that are flexible, mechanically strong and robust. The developed materials have immense capability as actuators for various applications including in biomimetics and robotics. MDPI 2022-02-10 /pmc/articles/PMC8879763/ /pubmed/35215581 http://dx.doi.org/10.3390/polym14040668 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Luqman, Mohammad
Shaikh, Hamid M.
Anis, Arfat
Al-Zahrani, Saeed M.
Alam, Mohammad Asif
A Convenient and Simple Ionic Polymer-Metal Composite (IPMC) Actuator Based on a Platinum-Coated Sulfonated Poly(ether ether ketone)–Polyaniline Composite Membrane
title A Convenient and Simple Ionic Polymer-Metal Composite (IPMC) Actuator Based on a Platinum-Coated Sulfonated Poly(ether ether ketone)–Polyaniline Composite Membrane
title_full A Convenient and Simple Ionic Polymer-Metal Composite (IPMC) Actuator Based on a Platinum-Coated Sulfonated Poly(ether ether ketone)–Polyaniline Composite Membrane
title_fullStr A Convenient and Simple Ionic Polymer-Metal Composite (IPMC) Actuator Based on a Platinum-Coated Sulfonated Poly(ether ether ketone)–Polyaniline Composite Membrane
title_full_unstemmed A Convenient and Simple Ionic Polymer-Metal Composite (IPMC) Actuator Based on a Platinum-Coated Sulfonated Poly(ether ether ketone)–Polyaniline Composite Membrane
title_short A Convenient and Simple Ionic Polymer-Metal Composite (IPMC) Actuator Based on a Platinum-Coated Sulfonated Poly(ether ether ketone)–Polyaniline Composite Membrane
title_sort convenient and simple ionic polymer-metal composite (ipmc) actuator based on a platinum-coated sulfonated poly(ether ether ketone)–polyaniline composite membrane
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8879763/
https://www.ncbi.nlm.nih.gov/pubmed/35215581
http://dx.doi.org/10.3390/polym14040668
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