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Effect of Impregnated Phenolic Resins on the Cellulose Membrane for Polymeric Insulator

In this study, a cellulose membrane (CM) was chemically treated with phenolic (PF) resin to improve its performance as a polymeric insulator. The CM was prepared from kenaf pulp, and the PF was synthesized from oil palm empty fruit (EFB) fibre. Four different concentrations of synthesized PF resin (...

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Autores principales: Syed Hashim, Sharifah Nurul Ain, Zakaria, Sarani, Chia, Chin Hua, Zainuddin, Zalita, Rosenau, Thomas, Syed Jaafar, Sharifah Nabihah
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8879978/
https://www.ncbi.nlm.nih.gov/pubmed/35207028
http://dx.doi.org/10.3390/membranes12020106
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author Syed Hashim, Sharifah Nurul Ain
Zakaria, Sarani
Chia, Chin Hua
Zainuddin, Zalita
Rosenau, Thomas
Syed Jaafar, Sharifah Nabihah
author_facet Syed Hashim, Sharifah Nurul Ain
Zakaria, Sarani
Chia, Chin Hua
Zainuddin, Zalita
Rosenau, Thomas
Syed Jaafar, Sharifah Nabihah
author_sort Syed Hashim, Sharifah Nurul Ain
collection PubMed
description In this study, a cellulose membrane (CM) was chemically treated with phenolic (PF) resin to improve its performance as a polymeric insulator. The CM was prepared from kenaf pulp, and the PF was synthesized from oil palm empty fruit (EFB) fibre. Four different concentrations of synthesized PF resin (5, 10, 15, and 20 wt.%) were impregnated under wet or dry conditions. Thermal analysis of the phenolic cellulose membrane (PCM) showed that the samples had good chemical interaction and compatibility. The PF uptake in the wet phenolic cellulose membrane (PCMW) was higher than in the dry phenolic cellulose membrane (PCMD). During the PF uptake, the CM underwent solvent exchange and absorption in wet and dry membranes, respectively. This difference also affected the crosslinking of PCM samples via the formation of methylene bridges. Due to the PF treatment, the PCM showed lower water absorption than CM. The PF concentrations also affect the surface roughness and electrical properties of PCM samples. These findings prove that PCM can be used as a renewable and green polymer electrical insulator.
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spelling pubmed-88799782022-02-26 Effect of Impregnated Phenolic Resins on the Cellulose Membrane for Polymeric Insulator Syed Hashim, Sharifah Nurul Ain Zakaria, Sarani Chia, Chin Hua Zainuddin, Zalita Rosenau, Thomas Syed Jaafar, Sharifah Nabihah Membranes (Basel) Article In this study, a cellulose membrane (CM) was chemically treated with phenolic (PF) resin to improve its performance as a polymeric insulator. The CM was prepared from kenaf pulp, and the PF was synthesized from oil palm empty fruit (EFB) fibre. Four different concentrations of synthesized PF resin (5, 10, 15, and 20 wt.%) were impregnated under wet or dry conditions. Thermal analysis of the phenolic cellulose membrane (PCM) showed that the samples had good chemical interaction and compatibility. The PF uptake in the wet phenolic cellulose membrane (PCMW) was higher than in the dry phenolic cellulose membrane (PCMD). During the PF uptake, the CM underwent solvent exchange and absorption in wet and dry membranes, respectively. This difference also affected the crosslinking of PCM samples via the formation of methylene bridges. Due to the PF treatment, the PCM showed lower water absorption than CM. The PF concentrations also affect the surface roughness and electrical properties of PCM samples. These findings prove that PCM can be used as a renewable and green polymer electrical insulator. MDPI 2022-01-18 /pmc/articles/PMC8879978/ /pubmed/35207028 http://dx.doi.org/10.3390/membranes12020106 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Syed Hashim, Sharifah Nurul Ain
Zakaria, Sarani
Chia, Chin Hua
Zainuddin, Zalita
Rosenau, Thomas
Syed Jaafar, Sharifah Nabihah
Effect of Impregnated Phenolic Resins on the Cellulose Membrane for Polymeric Insulator
title Effect of Impregnated Phenolic Resins on the Cellulose Membrane for Polymeric Insulator
title_full Effect of Impregnated Phenolic Resins on the Cellulose Membrane for Polymeric Insulator
title_fullStr Effect of Impregnated Phenolic Resins on the Cellulose Membrane for Polymeric Insulator
title_full_unstemmed Effect of Impregnated Phenolic Resins on the Cellulose Membrane for Polymeric Insulator
title_short Effect of Impregnated Phenolic Resins on the Cellulose Membrane for Polymeric Insulator
title_sort effect of impregnated phenolic resins on the cellulose membrane for polymeric insulator
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8879978/
https://www.ncbi.nlm.nih.gov/pubmed/35207028
http://dx.doi.org/10.3390/membranes12020106
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