Trimesityltriangulene: a persistent derivative of Clar's hydrocarbon

Triangulene, known as Clar's hydrocarbon, is a prototypical non-Kekulé diradical comprised of six benzenoid rings fused in a triangular shape. We synthesized and characterized its trimesityl derivative, illustrating that three bulky substituents installed in the centers of the zigzag edges suff...

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Autores principales: Valenta, Leoš, Mayländer, Maximilian, Kappeler, Pia, Blacque, Olivier, Šolomek, Tomáš, Richert, Sabine, Juríček, Michal
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8886921/
https://www.ncbi.nlm.nih.gov/pubmed/35156113
http://dx.doi.org/10.1039/d2cc00352j
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author Valenta, Leoš
Mayländer, Maximilian
Kappeler, Pia
Blacque, Olivier
Šolomek, Tomáš
Richert, Sabine
Juríček, Michal
author_facet Valenta, Leoš
Mayländer, Maximilian
Kappeler, Pia
Blacque, Olivier
Šolomek, Tomáš
Richert, Sabine
Juríček, Michal
author_sort Valenta, Leoš
collection PubMed
description Triangulene, known as Clar's hydrocarbon, is a prototypical non-Kekulé diradical comprised of six benzenoid rings fused in a triangular shape. We synthesized and characterized its trimesityl derivative, illustrating that three bulky substituents installed in the centers of the zigzag edges suffice to protect all reactive positions. This work brings prospects to use triangulene and its open-shell analogs in spintronic materials via solution-phase synthesis.
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spelling pubmed-88869212022-03-24 Trimesityltriangulene: a persistent derivative of Clar's hydrocarbon Valenta, Leoš Mayländer, Maximilian Kappeler, Pia Blacque, Olivier Šolomek, Tomáš Richert, Sabine Juríček, Michal Chem Commun (Camb) Chemistry Triangulene, known as Clar's hydrocarbon, is a prototypical non-Kekulé diradical comprised of six benzenoid rings fused in a triangular shape. We synthesized and characterized its trimesityl derivative, illustrating that three bulky substituents installed in the centers of the zigzag edges suffice to protect all reactive positions. This work brings prospects to use triangulene and its open-shell analogs in spintronic materials via solution-phase synthesis. The Royal Society of Chemistry 2022-02-04 /pmc/articles/PMC8886921/ /pubmed/35156113 http://dx.doi.org/10.1039/d2cc00352j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Valenta, Leoš
Mayländer, Maximilian
Kappeler, Pia
Blacque, Olivier
Šolomek, Tomáš
Richert, Sabine
Juríček, Michal
Trimesityltriangulene: a persistent derivative of Clar's hydrocarbon
title Trimesityltriangulene: a persistent derivative of Clar's hydrocarbon
title_full Trimesityltriangulene: a persistent derivative of Clar's hydrocarbon
title_fullStr Trimesityltriangulene: a persistent derivative of Clar's hydrocarbon
title_full_unstemmed Trimesityltriangulene: a persistent derivative of Clar's hydrocarbon
title_short Trimesityltriangulene: a persistent derivative of Clar's hydrocarbon
title_sort trimesityltriangulene: a persistent derivative of clar's hydrocarbon
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8886921/
https://www.ncbi.nlm.nih.gov/pubmed/35156113
http://dx.doi.org/10.1039/d2cc00352j
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