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The Solvation-Induced Onsager Reaction Field Rather than the Double-Layer Field Controls CO(2) Reduction on Gold

[Image: see text] The selectivity and activity of the carbon dioxide reduction (CO(2)R) reaction are sensitive functions of the electrolyte cation. By measuring the vibrational Stark shift of in situ-generated CO on Au in the presence of alkali cations, we quantify the total electric field present a...

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Detalles Bibliográficos
Autores principales: Zhu, Quansong, Wallentine, Spencer K., Deng, Gang-Hua, Rebstock, Jaclyn A., Baker, L. Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8889607/
https://www.ncbi.nlm.nih.gov/pubmed/35252996
http://dx.doi.org/10.1021/jacsau.1c00512