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The Solvation-Induced Onsager Reaction Field Rather than the Double-Layer Field Controls CO(2) Reduction on Gold
[Image: see text] The selectivity and activity of the carbon dioxide reduction (CO(2)R) reaction are sensitive functions of the electrolyte cation. By measuring the vibrational Stark shift of in situ-generated CO on Au in the presence of alkali cations, we quantify the total electric field present a...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2022
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8889607/ https://www.ncbi.nlm.nih.gov/pubmed/35252996 http://dx.doi.org/10.1021/jacsau.1c00512 |