Visible-Light-Driven, Iridium-Catalyzed Hydrogen Atom Transfer: Mechanistic Studies, Identification of Intermediates, and Catalyst Improvements

[Image: see text] The harvesting of visible light is a powerful strategy for the synthesis of weak chemical bonds involving hydrogen that are below the thermodynamic threshold for spontaneous H(2) evolution. Piano-stool iridium hydride complexes are effective for the blue-light-driven hydrogenation...

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Detalles Bibliográficos
Autores principales: Park, Yoonsu, Tian, Lei, Kim, Sangmin, Pabst, Tyler P., Kim, Junho, Scholes, Gregory D., Chirik, Paul J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8889617/
https://www.ncbi.nlm.nih.gov/pubmed/35252990
http://dx.doi.org/10.1021/jacsau.1c00460

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8889617/
https://www.ncbi.nlm.nih.gov/pubmed/35252990
http://dx.doi.org/10.1021/jacsau.1c00460

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