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Hydration of Aliphatic Nitriles Catalyzed by an Osmium Polyhydride: Evidence for an Alternative Mechanism
[Image: see text] The hexahydride OsH(6)(P(i)Pr(3))(2) competently catalyzes the hydration of aliphatic nitriles to amides. The main metal species under the catalytic conditions are the trihydride osmium(IV) amidate derivatives OsH(3){κ(2)-N,O-[HNC(O)R]}(P(i)Pr(3))(2), which have been isolated and f...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2021
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8892838/ https://www.ncbi.nlm.nih.gov/pubmed/33904305 http://dx.doi.org/10.1021/acs.inorgchem.1c00380 |