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Effect of Water Evaporation on the Inhibition of Spontaneous Coal Combustion

[Image: see text] Spontaneous coal combustion is the primary cause of coal mine fires. During the production process, spontaneous coal combustion in the goaf is often affected by air leakage, which weakens or annuls the effect of inhibitors and leads to secondary oxidation. However, the action mecha...

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Autores principales: Han, Qing, Cui, Chuanbo, Jiang, Shuguang, Deng, Cunbao, Jin, Zhixin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8892916/
https://www.ncbi.nlm.nih.gov/pubmed/35252676
http://dx.doi.org/10.1021/acsomega.1c06418
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author Han, Qing
Cui, Chuanbo
Jiang, Shuguang
Deng, Cunbao
Jin, Zhixin
author_facet Han, Qing
Cui, Chuanbo
Jiang, Shuguang
Deng, Cunbao
Jin, Zhixin
author_sort Han, Qing
collection PubMed
description [Image: see text] Spontaneous coal combustion is the primary cause of coal mine fires. During the production process, spontaneous coal combustion in the goaf is often affected by air leakage, which weakens or annuls the effect of inhibitors and leads to secondary oxidation. However, the action mechanism of inhibitors on secondary oxidation spontaneous coal combustion remains unclear. Thus, this study analyzes the influence of moisture evaporation on the performance of a high-water-content physical inhibitor (HWPI) using the Carbolite temperature-programmed experiment, differential scanning calorimetry, scanning electron microscopy, and a MINI MR test. The results demonstrate that as the moisture content of the inhibitor decreased, after being treated with the HWPI and drying for 24 h, the concentrations of O(2), CO, and CO(2) were found to be lower than the gas concentration of raw coal, which showed that although the moisture content is reduced, the treated coal sample still has a lower spontaneous combustion tendency than the raw coal. The apparent activation energy was reduced, and the heat absorption per unit time decreased, which eventually weakened or annulled the effect of the HWPI. Future research should further improve existing inhibitor types to reduce the impact of secondary oxidation on spontaneous coal combustion caused by water evaporation.
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spelling pubmed-88929162022-03-03 Effect of Water Evaporation on the Inhibition of Spontaneous Coal Combustion Han, Qing Cui, Chuanbo Jiang, Shuguang Deng, Cunbao Jin, Zhixin ACS Omega [Image: see text] Spontaneous coal combustion is the primary cause of coal mine fires. During the production process, spontaneous coal combustion in the goaf is often affected by air leakage, which weakens or annuls the effect of inhibitors and leads to secondary oxidation. However, the action mechanism of inhibitors on secondary oxidation spontaneous coal combustion remains unclear. Thus, this study analyzes the influence of moisture evaporation on the performance of a high-water-content physical inhibitor (HWPI) using the Carbolite temperature-programmed experiment, differential scanning calorimetry, scanning electron microscopy, and a MINI MR test. The results demonstrate that as the moisture content of the inhibitor decreased, after being treated with the HWPI and drying for 24 h, the concentrations of O(2), CO, and CO(2) were found to be lower than the gas concentration of raw coal, which showed that although the moisture content is reduced, the treated coal sample still has a lower spontaneous combustion tendency than the raw coal. The apparent activation energy was reduced, and the heat absorption per unit time decreased, which eventually weakened or annulled the effect of the HWPI. Future research should further improve existing inhibitor types to reduce the impact of secondary oxidation on spontaneous coal combustion caused by water evaporation. American Chemical Society 2022-02-17 /pmc/articles/PMC8892916/ /pubmed/35252676 http://dx.doi.org/10.1021/acsomega.1c06418 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Han, Qing
Cui, Chuanbo
Jiang, Shuguang
Deng, Cunbao
Jin, Zhixin
Effect of Water Evaporation on the Inhibition of Spontaneous Coal Combustion
title Effect of Water Evaporation on the Inhibition of Spontaneous Coal Combustion
title_full Effect of Water Evaporation on the Inhibition of Spontaneous Coal Combustion
title_fullStr Effect of Water Evaporation on the Inhibition of Spontaneous Coal Combustion
title_full_unstemmed Effect of Water Evaporation on the Inhibition of Spontaneous Coal Combustion
title_short Effect of Water Evaporation on the Inhibition of Spontaneous Coal Combustion
title_sort effect of water evaporation on the inhibition of spontaneous coal combustion
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8892916/
https://www.ncbi.nlm.nih.gov/pubmed/35252676
http://dx.doi.org/10.1021/acsomega.1c06418
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