MoS(2)/MXene Aerogel with Conformal Heterogeneous Interfaces Tailored by Atomic Layer Deposition for Tunable Microwave Absorption

In the design of electromagnetic (EM) wave absorbing materials, it is still a great challenge to optimize the relationship between the attenuation capability and impedance matching synergistically. Herein, a 3D porous MoS(2)/MXene hybrid aerogel architecture with conformal heterogeneous interface has been built by atomic layer deposition (ALD) based on specific porous templates to optimize the microwave absorption (MA) performance comprehensively. The original porous structure of pristine Ti(3)C(2)T (x) aerogel used as templates can be preserved well during ALD fabrication, which prolongs the reflection and scattering path and ameliorates the dielectric loss. Meanwhile, plenty of heterointerfaces between MoS(2) and Ti(3)C(2)T (x) have been fabricated based on conformally ALD‐deposited MoS(2) with controlled thickness on the porous surfaces of the templates, which can effectively optimize the impedance matching and transform its response to EM waves from shielding into absorbing. Moreover, the interaction between the attenuation capability and impedance matching can also be modulated by the number of ALD cycle in MoS(2) fabrication. After optimization, MoS(2)/MXene hybrid aerogel obtained under 300 ALD cycles shows a minimum reflection loss of −61.65 dB at the thickness of 4.53 mm. In addition, its preferable lightweight, high surface area, mechanical, and hydrophobicity properties will also be conducive to further practical applications.